Birch Wood Surface Characterization after Treatment with Modified Phenol-Formaldehyde Oligomers

• Published in: Polymers Vol. 14; no. 4; p. 671
• Main Authors: Grinins, Juris, Iesalnieks, Mairis, Biziks, Vladimirs, Gritane, Ineta, Sosins, Guntis
• Format: Journal Article
• Language: English
• Published: Switzerland MDPI AG 10.02.2022; MDPI
• Subjects: Artificial weathering tests; birch wood; Caustic soda; Chlorides; color stability; Contact angle; Cracks; Esterification; fatty acid chlorides; Fatty acids; Hydrophobic surfaces; Hydrophobicity; Hydroxyl groups; Laboratories; Oligomers; Phenol formaldehyde; phenol-formaldehyde resin; Phenols; Polymer films; Polymers; Resins; Surface properties; Tetrahydrofuran; Water drops; Water sprays; Weathering; hydrophobicity; color stability; fatty acid chlorides; birch wood; phenol-formaldehyde resin
• ISSN: 2073-4360; 2073-4360
• DOI: 10.3390/polym14040671

Phenol-formaldehyde (PF) resins with well-established molecular sizes are promising treatment agents for wood bulk protection. However, due to the presence of hydroxyl groups on the periphery, the PF oligomers tend to absorb the water, which can lead to water penetration into the wood. To overcome this drawback different PF pre-polymers have been chemically modified with different long-chain fatty acid chlorides (FAC) via esterification. To obtain the modified PF (M-PF) resins, the PF pre-polymers with average molecular weight (M ) from 266 to 884 g/mol were esterified with decanoyl, lauroyl, myristoyl, palmitoyl, and stearoyl chloride in pyridine as the reaction medium. Silver birch ( ) wood specimens (15 × 70 × 150 mm ) were coated with M-PF pre-polymer 5% (w/w) solutions in tetrahydrofuran (THF), and hydrophobic properties of treated birch wood specimens were evaluated using surface contact angle (CA) measurements of water droplets. For all M-PF resin-treated specimens, CA was almost 2-2.5 times higher than for untreated wood (45°) and it remained 80-125° after 60 s. The aging properties of M-PF resin-coated birch wood were analyzed using artificial weathering with ultraviolet (UV) light and combination of both UV and water spray. Results clearly confirm, that the hydrophobic properties of M-PF-treated wood has short-term character and will gradually disappear during long-term application in outdoor conditions.