Preparation Methods of Polypropylene/Nano-Silica/Styrene-Ethylene-Butylene-Styrene Composite and Its Effect on Electrical Properties

• Published in: Polymers Vol. 11; no. 5; p. 797
• Main Authors: Gao, Mingze, Yang, Jiaming, Zhao, Hong, He, Hui, Hu, Ming, Xie, Shuhong
• Format: Journal Article
• Language: English
• Published: Switzerland MDPI AG 04.05.2019; MDPI
• Subjects: Block copolymers; Breakdown; Cables; Cross-linked polyethylene; Crystallization; DC breakdown; Dielectric properties; Direct current; Electrical properties; Impact strength; Insulation; Mechanical properties; nano-SiO2; Nanocomposites; Nanoparticles; Polymers; Polypropylene; Recycling; Scanning electron microscopy; SEBS; Silicon dioxide; Space charge; Styrenes; Thermodynamic properties; United States > US; China; nano-SiO2; polypropylene; SEBS; space charge; DC breakdown
• ISSN: 2073-4360; 2073-4360
• DOI: 10.3390/polym11050797

Compared with traditional insulation materials, such as cross-linked polyethylene (XLPE), polypropylene (PP) is famous for its better recyclable and thermal properties, as well as its good electrical performance. However, the problem of poor impact strength has restricted the application of pure PP in high-voltage, direct current (HVDC) cables. In this paper, styrene-ethylene-butylene-styrene block copolymer (SEBS) was used as a toughening filler, and nano-SiO was expected to improve the electric properties of the nano-composite. By controlling the masterbatch system, the dispersion characteristics of nano-SiO in the ternary composite system were changed. When PP/SiO was used as the masterbatch and then blended with SEBS, nano-SiO tended to disperse in the PP phase, and the number of nano-particles in the SEBS phase was lower. When PP/SEBS was used as the masterbatch, nano-SiO was distributed in both the PP phase and the SEBS phase. When SEBS/SiO was used as the masterbatch, nano-SiO tended to be dispersed in the SEBS phase. The different dispersion characteristics of nano-SiO changed the crystallization and mechanical properties of the ternary composite system and produced different electrical performance improvement effects. The results of our experiment revealed that the space charge suppression capability was positively correlated with the direct current (DC) breakdown strength improvement effect. Compared with the DC performance of 500 kV commercial XLPE materials, the self-made PP-based ternary composite system has better space charge suppression effects and higher DC breakdown strength. When nano-SiO was more dispersed in the PP phase, the space charge improvement effect was best. When the nano-SiO particles were more dispersed in the SEBS phase, the expected electrical property improvement was not obtained. Scanning electron microscopy showed that the nano-SiO particles in the SEBS phase were more dispersed at the interface than in the SEBS matrix, indicating that the nano-particles were poorly dispersed, which may be a reason why the electrical properties of the composite system were not significantly improved.