Determination of electron affinity of carbonyl radicals by means of negative ion mass spectrometry

Appearance energies of [M−H]− ions from carbonyl compounds R‐CO‐R′ (R,R′ = H, CH3, NH2, OH) have been measured by means of negative ion mass spectrometry in resonant electron capture mode. Values of electron affinity of the corresponding radicals, CH2C(X)O, NHC(X)O and OC(X)O, have been determine...

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Published inRapid communications in mass spectrometry Vol. 13; no. 12; pp. 1104 - 1108
Main Authors Muftakhov, Mars V., Vasil'ev, Yury V., Mazunov, Victor A.
Format Journal Article
LanguageEnglish
Published Chichester, UK John Wiley & Sons, Ltd 30.06.1999
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Summary:Appearance energies of [M−H]− ions from carbonyl compounds R‐CO‐R′ (R,R′ = H, CH3, NH2, OH) have been measured by means of negative ion mass spectrometry in resonant electron capture mode. Values of electron affinity of the corresponding radicals, CH2C(X)O, NHC(X)O and OC(X)O, have been determined. Copyright © 1999 John Wiley & Sons, Ltd.
Bibliography:ArticleID:RCM619
Russian Foundation for Basic Research - No. 98-03-33141
INTAS - No. 97-1245
istex:6A9C69B3258D852CE297367711650A5248D8CE8E
ark:/67375/WNG-4ZTX4NFB-N
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:0951-4198
1097-0231
DOI:10.1002/(SICI)1097-0231(19990630)13:12<1104::AID-RCM619>3.0.CO;2-C