Glaser Coupling at Metal Surfaces

On‐surface synthesis is a promising approach for constructing covalently bound nanostructures. However, the number of reliable chemical reactions suitable for on‐surface chemistry is very limited. Arylalkynes can be coupled at various surfaces in a novel 2D Glaser coupling (see picture). This approa...

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Bibliographic Details
Published inAngewandte Chemie (International ed.) Vol. 52; no. 14; pp. 4024 - 4028
Main Authors Gao, Hong-Ying, Wagner, Hendrik, Zhong, Dingyong, Franke, Jörn-Holger, Studer, Armido, Fuchs, Harald
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 02.04.2013
WILEY‐VCH Verlag
Wiley
Wiley Subscription Services, Inc
EditionInternational ed. in English
Subjects
Chemical reactions
Chemistry
Chemistry, Multidisciplinary
conjugation
Construction
Construction materials
Covalence
CC coupling
Joining
Metal surfaces
Nanostructure
Physical Sciences
polymerization
scanning tunneling microscopy
Science & Technology
surface chemistry
Synthesis
CC coupling
polymerization
POLYMERS
surface chemistry
CHEMISTRY
FABRICATION
conjugation
scanning tunneling microscopy
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Summary:On‐surface synthesis is a promising approach for constructing covalently bound nanostructures. However, the number of reliable chemical reactions suitable for on‐surface chemistry is very limited. Arylalkynes can be coupled at various surfaces in a novel 2D Glaser coupling (see picture). This approach can be used for constructing conjugated materials directly on surfaces.
Bibliography:ark:/67375/WNG-C75CWBNC-M
We thank the Deutsche Forschungsgemeinschaft (SFB 858, TRR 61) for financial support and Prof. Lifeng Chi for helpful discussions. H.-Y.G. was supported by the Alexander von Humboldt-Foundation.
ArticleID:ANIE201208597
Deutsche Forschungsgemeinschaft - No. SFB 858; No. TRR 61
istex:FF38D4A07880A2E473E50BBE9F0542570079B984
These authors contributed equally to this work.
We thank the Deutsche Forschungsgemeinschaft (SFB 858, TRR 61) for financial support and Prof. Lifeng Chi for helpful discussions. H.‐Y.G. was supported by the Alexander von Humboldt‐Foundation.
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
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ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201208597