Engineering Catalyst Microenvironments for Metal-Catalyzed Hydrogenation of Biologically Derived Platform Chemicals

• Published in: Angewandte Chemie (International ed.) Vol. 53; no. 47; pp. 12718 - 12722
• Main Authors: Schwartz, Thomas J., Johnson, Robert L., Cardenas, Javier, Okerlund, Adam, Da Silva, Nancy A., Schmidt-Rohr, Klaus, Dumesic, James A.
• Format: Journal Article
• Language: English
• Published: Weinheim WILEY-VCH Verlag 17.11.2014; WILEY‐VCH Verlag; Wiley Subscription Services, Inc
• Edition: International ed. in English
• Subjects: Alcohols; Amino Acids - chemistry; biomass; biorenewable chemicals; Catalysis; catalyst stability; Catalysts; Catalytic Domain; Deactivation; Formations; Hydrogenation; Impurities; Metals, Heavy - antagonists & inhibitors; Metals, Heavy - chemistry; Molecular Structure; nanocomposites; Nanoparticles; Palladium; Polyvinyl Alcohol - chemistry; Polyvinyl alcohols; Pyrones - chemistry; biorenewable chemicals; biomass; catalyst stability; hydrogenation; nanocomposites
• ISSN: 1433-7851; 1521-3773
• DOI: 10.1002/anie.201407615

It is shown that microenvironments formed around catalytically active sites mitigate catalyst deactivation by biogenic impurities that are present during the production of biorenewable chemicals from biologically derived species. Palladium and ruthenium catalysts are inhibited by the presence of sulfur‐containing amino acids; however, these supported metal catalysts are stabilized by overcoating with poly(vinyl alcohol) (PVA), which creates a microenvironment unfavorable for biogenic impurities. Moreover, deactivation of Pd catalysts by carbon deposition from the decomposition of highly reactive species is suppressed by the formation of bimetallic PdAu nanoparticles. Thus, a PVA‐overcoated PdAu catalyst was an order of magnitude more stable than a simple Pd catalyst in the hydrogenation of triacetic acid lactone, which is the first step in the production of biobased sorbic acid. A PVA‐overcoated Ru catalyst showed a similar improvement in stability during lactic acid hydrogenation to propylene glycol in the presence of methionine. The surface properties of supported metal hydrogenation catalysts are modified by the formation of microenvironments inside the catalyst pores and surrounding the metal nanoparticles. These microenvironments are derived from poly(vinyl alcohol) (PVA), and they are used to mitigate catalyst deactivation that is due to biogenic impurities.