Outdoor urban nanomaterials: The emergence of a new, integrated, and critical field of study

• Published in: The Science of the total environment Vol. 557-558; pp. 740 - 753
• Main Authors: Baalousha, Mohammed, Yang, Yi, Vance, Marina E., Colman, Benjamin P., McNeal, Samantha, Xu, Jie, Blaszczak, Joanna, Steele, Meredith, Bernhardt, Emily, Hochella, Michael F.
• Format: Journal Article
• Language: English
• Published: Netherlands Elsevier B.V 01.07.2016; Elsevier
• Subjects: Atmosphere; Cities; Engineered nanomaterials; Environmental Monitoring; Environmental Pollutants; Incidental nanomaterials; Manufactured Materials; NANOSCIENCE AND NANOTECHNOLOGY; Nanostructures; Nanotechnology industry; Storm water; Surface water; Urban environment; Cities; Incidental nanomaterials; Urban environment; Storm water; Atmosphere; Surface water; Engineered nanomaterials
• ISSN: 0048-9697; 1879-1026
• DOI: 10.1016/j.scitotenv.2016.03.132

Engineered nanomaterials (ENMs) are currently widely incorporated in the outdoor urban environmental fabric and numerous new applications and products containing ENMs are expected in the future. As has been shown repeatedly, products containing ENMs have the potential, at some point in their lifetime, to release ENMs into their surrounding environment. However, the expanding body in environmental nanomaterial research has not yet shifted toward ENMs in the context of the complex outdoor urban environment. This is especially surprising because the world's human populations are on a steady march toward more and more urbanization and technological development, accompanied with increased applications for ENMs in the outdoor urban environment. Our objective for this paper is therefore to review, assess, and provide new information in this emerging field. We provide an overview of nanomaterials (NMs, encompassing both ENMs and incidental nanomaterials, INMs) that are likely to be released in the urban environment from outdoor sources by discussing 1) the applications of ENMs that may lead to release of ENMs in urban areas, 2) the recently published data on the release of ENMs from novel nano-enabled applications in the outdoor urban environment, 3) the available literature on the occurrence of INMs in the atmosphere and within/on dust particles, and 4) the potential pathways and fate of NMs in the outdoor urban environment. This review is then followed by three case studies demonstrating the importance of NMs in the outdoor urban environment. The first and second case studies illustrate the occurrence of NMs in urban dust and stormwater ponds, respectively, whereas the third case study discusses the lessons learned from the release of NMs (e.g. Pt, ph and Rh) from automotive vehicle catalytic convertors. This article ends with a discussion of the research priorities needed to advance this emerging field of “outdoor urban nanomaterials” and to assess the potential risks of NMs in the context of urban environments. [Display omitted] •ENMs are being incorporated and released in the outdoor urban environment.•Iron oxide, PbS and Ca2SiO4 NMs were identified in atmospheric particulate matter.•Iron oxide, TiO2, ZnO, ZnS NMs have been identified in stormwater ponds.