Heterogenization of Pd(II) complexes as catalysts for the Suzuki-Miyaura reaction

• Published in: Applied catalysis. A, General Vol. 627; p. 118381
• Main Authors: De Tovar, Jonathan, Rataboul, Franck, Djakovitch, Laurent
• Format: Journal Article
• Language: English
• Published: Amsterdam Elsevier B.V 25.10.2021; Elsevier Science SA; Elsevier
• Subjects: Catalysis; Catalysts; Chemical reactions; Chemical Sciences; Chemical synthesis; Environment and Society; Environmental Sciences; Fine chemicals; Heterogeneous homogeneous catalysis; Metal oxides; N-heterocyclic carbene; Palladium complexes; Palladium nanoparticles; Phosphines; Recyclability; Suzuki-Miyaura; N-heterocyclic carbene; Metal oxides; Heterogeneous homogeneous catalysis; Palladium complexes; Suzuki-Miyaura; Palladium nanoparticles; Phosphines
• ISSN: 0926-860X; 1873-3875
• DOI: 10.1016/j.apcata.2021.118381

This review highlights the potential application and understanding of Pd(II) complexes anchoring onto different supports as catalytic systems for the Suzuki-Miyaura reaction. The combination of the high reactivity of Pd complexes with their facile separation, purification and recyclability makes these systems promising catalysts for the industrial synthesis of fine chemicals. This review focuses on the general developments in this research area in the last three decades comprising the most recent achievements and understanding of these heterogenized systems. [Display omitted] •Review on the effect of the support for palladium complexes in the Suzuki-Miyaura reaction.•Discussion on the preparation methods for the supports.•Discussion on the grafting procedures for the palladium complexes.•Catalytic performance, leaching and recyclability of the catalyst depends on the nature of the support and that of the palladium complex.