Electrolytic properties of lithium chelatophosphates and application to lithium batteries

• Published in: Journal of power sources Vol. 142; no. 1; pp. 333 - 338
• Main Authors: Nanbu, Noritoshi, Tsuchiya, Koji, Sasaki, Yukio
• Format: Journal Article
• Language: English
• Published: Lausanne Elsevier B.V 24.03.2005; Elsevier Sequoia
• Subjects: Addition effect; Applied sciences; Cycling efficiency; Direct energy conversion and energy accumulation; Electrical engineering. Electrical power engineering; Electrical power engineering; Electrochemical conversion: primary and secondary batteries, fuel cells; Energy; Energy. Thermal use of fuels; Equipments for energy generation and conversion: thermal, electrical, mechanical energy, etc; Exact sciences and technology; Fuel cells; Lithium battery; Lithium chelatophosphate; Orphology; Specific conductivity; Lithium battery; Specific conductivity; Lithium chelatophosphate; Orphology; Addition effect; Cycling efficiency; Phosphates; Viscosity; Prototype; Anode; Electric vehicle; Dissolution; Discharge charge cycle; Lithium phosphate; Vanadium oxide; Carbonates
• ISSN: 0378-7753; 1873-2755
• DOI: 10.1016/j.jpowsour.2004.09.003

Growing interest has been focused on the development of lithium salts with fluorine atoms and on their application to electric vehicles. We have investigated the electrolytic properties of lithium tris[3-fluoro-1,2-benzenediolato(2-)- O, O′]phosphate (3-FLTBP) and lithium tris[1,2-benzenediolato(2-)- O, O′]phosphate (LTBP) and the discharge characteristics of prototype Li/V 2O 5 cells containing ethylene carbonate (EC)-based chain carbonate or EC-based tetrahydrofuran (THF) binary solutions. The introduction of fluorine atoms into a chelatophosphate anion can lead to an increase of conductivity in spite of the enhanced viscosity. Furthermore, we report the coulombic efficiency of the deposition/dissolution cycling for a lithium metal (cycling efficiency of a lithium anode) and the morphology of passivating films formed on a Ni electrode surface in the EC-chain carbonate and the EC–THF binary systems. The addition of a small amount of the 3-FLTBP to EC-based chain carbonate binary solutions containing LiPF 6 improves the cycling efficiency. When the cycling efficiency becomes higher, it is found by scanning electron microscope (SEM) that the surface film consists of grains of regular size and that the thickness is relatively thin.