Thin Film Structure of Triisopropylsilylethynyl-Functionalized Pentacene and Tetraceno[2,3-b]thiophene from Grazing Incidence X-Ray Diffraction

The specific molecular arrangement of triisopropylsilylethynyl (TIPS)‐functionalized acenes is widely considered to be the origin of the high performance of TIPS‐pentacene thin film devices. However, detailed information on the molecular packing is so far only available for bulk single crystals, and...

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Published inAdvanced materials (Weinheim) Vol. 23; no. 1; pp. 127 - 131
Main Authors Mannsfeld, Stefan C. B., Tang, Ming Lee, Bao, Zhenan
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 04.01.2011
WILEY‐VCH Verlag
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Abstract The specific molecular arrangement of triisopropylsilylethynyl (TIPS)‐functionalized acenes is widely considered to be the origin of the high performance of TIPS‐pentacene thin film devices. However, detailed information on the molecular packing is so far only available for bulk single crystals, and the molecular packing of TIPS‐functionalized acenes in thin films has not been directly determined to date. A combination of ultrabright synchrotron grazing incidence X‐ray diffraction (GIXD) and crystallographic refinement calculations is utilized to obtain precise information about the molecular packing of two high‐performance TIPS‐functionalized semiconductors, TIPS‐ tetraceno[2,3‐b]thiophene and TIPS‐pentacene, in thin films on silicon oxide.
AbstractList The specific molecular arrangement of triisopropylsilylethynyl (TIPS)‐functionalized acenes is widely considered to be the origin of the high performance of TIPS‐pentacene thin film devices. However, detailed information on the molecular packing is so far only available for bulk single crystals, and the molecular packing of TIPS‐functionalized acenes in thin films has not been directly determined to date. A combination of ultrabright synchrotron grazing incidence X‐ray diffraction (GIXD) and crystallographic refinement calculations is utilized to obtain precise information about the molecular packing of two high‐performance TIPS‐functionalized semiconductors, TIPS‐ tetraceno[2,3‐b]thiophene and TIPS‐pentacene, in thin films on silicon oxide.
Author Tang, Ming Lee
Mannsfeld, Stefan C. B.
Bao, Zhenan
Author_xml – sequence: 1
  givenname: Stefan C. B.
  surname: Mannsfeld
  fullname: Mannsfeld, Stefan C. B.
  email: mannsfel@slac.stanford.edu
  organization: Stanford Synchrotron Radiation Lightsource, Menlo Park, CA, U.S.A
– sequence: 2
  givenname: Ming Lee
  surname: Tang
  fullname: Tang, Ming Lee
  organization: Department of Chemical Engineering, Stanford University, CA, U.S.A
– sequence: 3
  givenname: Zhenan
  surname: Bao
  fullname: Bao, Zhenan
  organization: Department of Chemical Engineering, Stanford University, CA, U.S.A
BackLink https://www.ncbi.nlm.nih.gov/pubmed/21104808$$D View this record in MEDLINE/PubMed
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Snippet The specific molecular arrangement of triisopropylsilylethynyl (TIPS)‐functionalized acenes is widely considered to be the origin of the high performance of...
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SubjectTerms Diffraction
Grazing incidence
Molecular Structure
Naphthacenes - chemistry
Organosilicon Compounds - chemistry
Pentacene
Thin films
Thiophenes - chemistry
X-Ray Diffraction
X-rays
Title Thin Film Structure of Triisopropylsilylethynyl-Functionalized Pentacene and Tetraceno[2,3-b]thiophene from Grazing Incidence X-Ray Diffraction
URI https://api.istex.fr/ark:/67375/WNG-B932HTTR-C/fulltext.pdf
https://onlinelibrary.wiley.com/doi/abs/10.1002%2Fadma.201003135
https://www.ncbi.nlm.nih.gov/pubmed/21104808
https://search.proquest.com/docview/821596627
https://search.proquest.com/docview/880687122
Volume 23
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