Growth of One-Dimensional Nanostructures in Porous Polymer-Derived Ceramics by Catalyst-Assisted Pyrolysis. Part II: Cobalt Catalyst

• Published in: Journal of the American Ceramic Society Vol. 93; no. 11; pp. 3709 - 3719
• Main Authors: Vakifahmetoglu, Cekdar, Colombo, Paolo, Carturan, Sara Maria, Pippel, Eckhard, Woltersdorf, Jörg
• Format: Journal Article
• Language: English
• Published: Malden, USA Blackwell Publishing Inc 01.11.2010; Wiley Subscription Services, Inc
• Subjects: Catalysts; Ceramics; Cobalt; Crystal structure; Iron; Materials science; Nanostructure; Nanostructured ceramics; Nanowires; Pyrolysis; Silicon carbide; Silicon nitride; Temperature effects
• ISSN: 0002-7820; 1551-2916
• DOI: 10.1111/j.1551-2916.2010.03974.x

Via catalyst‐assisted pyrolysis, Si3N4 and SiC nanowires were produced on the cell walls of polymer‐derived ceramic foams. The pyrolysis atmosphere and temperature were the main parameters affecting their development: silicon nitride single‐crystal nanowires formed under nitrogen, while silicon carbide ones were produced under argon, and their amount increased with the increasing pyrolysis temperature. Brunauer–Emmett–Teller analysis showed that the presence of the nanowires afforded high specific surface area (SSA) values to the macroporous ceramic foams, ranging from 10 to 110 m2/g. Co‐containing samples developed higher SSA values, especially after pyrolysis at 1400°C in N2, than samples containing Fe as a catalyst. The differences were explained in terms of morphology (diameter and assemblage), which depended on the processing conditions and the catalyst type (Co or Fe).