Pyrrole N–H anion complexes

Synthetic pyrrole-based anion receptors date back to the 1990s. They have been extensively developed in the context of macrocyclic systems such as expanded porphyrins and calixpyrroles, and related systems. The chemistry of open-chain pyrrolic systems is, in many respects, no less venerable. It also...

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Published inCoordination chemistry reviews Vol. 345; no. C; pp. 281 - 296
Main Authors Vargas-Zúñiga, Gabriela I., Sessler, Jonathan L.
Format Journal Article
LanguageEnglish
Published Switzerland Elsevier B.V 15.08.2017
Elsevier
Subjects
Anion binding
Chemistry
Hydrogen-bonding
Prodigiosin
Pyrrole
Receptor
Recognition
UDP
GTP
AMP
Prodigiosin
CMP
PPi
GMP
ADP
PAMAM
UTP
TTP
TBA
Hydrogen-bonding
Receptor
POPC
Pyrrole
Anion binding
ATP
CTP
Recognition
Anion Binding
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Summary:Synthetic pyrrole-based anion receptors date back to the 1990s. They have been extensively developed in the context of macrocyclic systems such as expanded porphyrins and calixpyrroles, and related systems. The chemistry of open-chain pyrrolic systems is, in many respects, no less venerable. It also has more direct analogy to naturally occurring pyrrole-based anion binding motifs. However, it has not been the subject of a comprehensive review. Presented herein is a summary of efforts devoted to the creation of de novo pyrrole-based receptors, as well as the anion recognition chemistry of naturally occurring pyrrolic systems as prodigiosins and their synthetic analogues.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
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content type line 23
FG02-01ER15186
USDOE Office of Science (SC)
ISSN:0010-8545
1873-3840
DOI:10.1016/j.ccr.2017.04.004