Melt Spinning of Flexible and Conductive Immiscible Thermoplastic/Elastomer Monofilament for Water Detection

• Published in: Nanomaterials (Basel, Switzerland) Vol. 12; no. 1; p. 92
• Main Authors: Regnier, Julie, Cayla, Aurélie, Campagne, Christine, Devaux, Éric
• Format: Journal Article
• Language: English
• Published: Switzerland MDPI AG 29.12.2021; MDPI
• Subjects: Addition polymerization; Carbon; Carbon nanotubes; Composite materials; Concrete; Conducting polymers; conductive polymer composite; Elastomers; Electrical conductivity; Electrical resistivity; Extrusion; filament; Fillers; Fluidity; Humidity; immiscible thermoplastic/elastomer blend; Melt spinning; Miscibility; Morphology; Nanotechnology; Nanotubes; Percolation; Polyamide resins; Polyamides; Polymer matrix composites; Polymers; Propylene; Rheological properties; Rheology; Short circuits; Textiles; Viscosity; water leak detection; Yarn; United States > US; water leak detection; conductive polymer composite; carbon nanotubes; filament; immiscible thermoplastic/elastomer blend
• ISSN: 2079-4991; 2079-4991
• DOI: 10.3390/nano12010092

In many textile fields, such as industrial structures or clothes, one way to detect a specific liquid leak is the electrical conductivity variation of a yarn. This yarn can be developed using melt spun of Conductive Polymer Composites (CPCs), which blend insulating polymer and electrically conductive fillers. This study examines the influence of the proportions of an immiscible thermoplastic/elastomer blend for its implementation and its water detection. The thermoplastic polymer used for the detection property is the polyamide 6.6 (PA6.6) filled with enough carbon nanotubes (CNT) to exceed the percolation threshold. However, the addition of fillers decreases the polymer fluidity, resulting in the difficulty to implement the CPC. Using an immiscible polymers blend with an elastomer, which is a propylene-based elastomer (PBE) permits to increase this fluidity and to create a flexible conductive monofilament. After characterizations (morphology, rheological and mechanical) of this blend (PA6.6 /PBE) in different proportions, two principles of water detection are established and carried out with the monofilaments: the principle of absorption and the short circuit. It is found that the morphology of the immiscible polymer blend had a significant role in the water detection.