Extended conjugated microporous polymers for photocatalytic hydrogen evolution from water

Conjugated microporous polymers (CMPs) have been used as photocatalysts for hydrogen production from water in the presence of a sacrificial electron donor. The relative importance of the linker geometry, the co-monomer linker length, and the degree of planarisation were studied with respect to the p...

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Published inChemical communications (Cambridge, England) Vol. 52; no. 65; pp. 18 - 111
Main Authors Sprick, Reiner Sebastian, Bonillo, Baltasar, Sachs, Michael, Clowes, Rob, Durrant, James R, Adams, Dave J, Cooper, Andrew I
Format Journal Article
LanguageEnglish
Published England 04.08.2016
Subjects
Hydrogen evolution
Hydrogen production
Photocatalysis
Photocatalysts
Polymers
porous media
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Summary:Conjugated microporous polymers (CMPs) have been used as photocatalysts for hydrogen production from water in the presence of a sacrificial electron donor. The relative importance of the linker geometry, the co-monomer linker length, and the degree of planarisation were studied with respect to the photocatalytic hydrogen evolution rate. Conjugated microporous polymers (CMPs) have been used as photocatalysts for hydrogen production from water in the presence of a sacrificial electron donor.
Bibliography:Electronic supplementary information (ESI) available: Full experimental details, gas sorption isotherms, UV-vis, PL, and FT-IR spectra, PXRD, SEM, hydrogen evolution experiments, suspension PL spectra, and TCSPC experiments. See DOI
10.1039/c6cc03536a
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:1359-7345
1364-548X
1364-548X
DOI:10.1039/c6cc03536a