Catalytic Amination of Biomass-Based Alcohols

Can I borrow hydrogen? Direct amination of biomass‐derived platform alcohols can be efficiently performed through the borrowing hydrogen mechanism, offering high activity and selectivity at low‐to‐moderate temperatures. Unlike nucleophilic substitution, the catalyst behaves as a tandem system involv...

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Bibliographic Details
Published inChemSusChem Vol. 7; no. 3; pp. 720 - 722
Main Authors Pera-Titus, Marc, Shi, Feng
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 01.03.2014
WILEY‐VCH Verlag
Wiley Subscription Services, Inc
Subjects
Alcohols - chemistry
Amination
ammonia
bio-alcohol
Biomass
Catalysis
heterogeneous catalysis
sustainable chemistry
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Summary:Can I borrow hydrogen? Direct amination of biomass‐derived platform alcohols can be efficiently performed through the borrowing hydrogen mechanism, offering high activity and selectivity at low‐to‐moderate temperatures. Unlike nucleophilic substitution, the catalyst behaves as a tandem system involving the temporary removal of H2 from the reaction medium.
Bibliography:ark:/67375/WNG-HHJVHF29-N
ANR (SHAPEs)
istex:BF8728616E8FF15D31BABF67B8FB03288D6E98AD
ArticleID:CSSC201301095
NSFC - No. 21073208
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:1864-5631
1864-564X
DOI:10.1002/cssc.201301095