New Phosphorus Ligands for the Rhodium-Catalyzed Isomerization/Hydroformylation of Internal Octenes

Going up! n‐Selectivity and activity can be increased simultaneously in hydroformylation by the use of novel hybrid ligands such as 1 containing O‐acylphosphite groups. For the first time these ligands deliver impressively n‐selective rhodium‐catalyzed hydroformylation of internal octenes, and this...

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Published inAngewandte Chemie (International ed.) Vol. 40; no. 9; pp. 1696 - 1698
Main Authors Selent, Detlef, Hess, Dieter, Wiese, Klaus-Diether, Röttger, Dirk, Kunze, Christine, Börner, Armin
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag GmbH 04.05.2001
WILEY‐VCH Verlag GmbH
Wiley
Subjects
Chemistry
Chemistry, Multidisciplinary
homogeneous catalysis
hydroformylation
isomerization
P ligands
Physical Sciences
rhodium
Science & Technology
OLEFINS
HYDROFORMYLATION
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Summary:Going up! n‐Selectivity and activity can be increased simultaneously in hydroformylation by the use of novel hybrid ligands such as 1 containing O‐acylphosphite groups. For the first time these ligands deliver impressively n‐selective rhodium‐catalyzed hydroformylation of internal octenes, and this with an industrial relevant catalytic activity.
Bibliography:ark:/67375/WNG-JMQC1KW7-Q
ArticleID:ANIE16960
istex:82818C4B9353EF2F4197EC7A6071BFC6E651F2C5
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:1433-7851
1521-3773
DOI:10.1002/1521-3773(20010504)40:9<1696::AID-ANIE16960>3.0.CO;2-2