Heavier pnictogens - treasures for optical electronic and reactivity tuning

We highlight recent advances in organopnictogen chemistry contrasting the properties of lighter and heavier pnictogens. Exploring new bonding situations, discovering unprecedented reactivities and producing fascinating opto-electronic materials are some of the most prominent directions of current or...

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Published inDalton transactions : an international journal of inorganic chemistry Vol. 48; no. 14; pp. 446 - 4466
Main Authors Green, Joshua P, Wells, Jordann A. L, Orthaber, Andreas
Format Journal Article
LanguageEnglish
Published England Royal Society of Chemistry 2019
Subjects
Electronic materials
Optoelectronics
Organic chemistry
Reactivity
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Summary:We highlight recent advances in organopnictogen chemistry contrasting the properties of lighter and heavier pnictogens. Exploring new bonding situations, discovering unprecedented reactivities and producing fascinating opto-electronic materials are some of the most prominent directions of current organopnicogen research. Expanding the chemical toolbox towards the heavier group 15 elements will continue to create new opportunities to tailor molecular properties for small molecule activation/reactivity and materials applications alike. This frontier article illustrates the elemental substitution approach in selected literature examples. We highlight recent advances in organopnictogen chemistry contrasting the properties of lighter and heavier pnictogens.
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ISSN:1477-9226
1477-9234
1477-9234
DOI:10.1039/c9dt00574a