Water ingress into and climate dependent lifetime of organic photovoltaic cells investigated by calcium corrosion tests
The degradation of non-encapsulated, small-molecule organic solar cells based on ZnPc (zinc phthalocyanine)/C60 with an aluminum top electrode is investigated under different climate conditions and correlated with the water barrier performance of the aluminum electrode layer. The degradation of the...
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Published in | Solar energy materials and solar cells Vol. 120; pp. 685 - 690 |
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Main Authors | , , , , , , , |
Format | Journal Article |
Language | English |
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Amsterdam
Elsevier B.V
01.01.2014
Elsevier |
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Abstract | The degradation of non-encapsulated, small-molecule organic solar cells based on ZnPc (zinc phthalocyanine)/C60 with an aluminum top electrode is investigated under different climate conditions and correlated with the water barrier performance of the aluminum electrode layer. The degradation of the solar cells turns out to be dominated by water and can be well predicted by the corrosion of calcium – a sensor for water – under the same conditions. By several independent techniques, an amount of 20±7mg(H2O)m−2 is determined to reduce the solar cell efficiency to 50% of the initial value, independent of humidity and temperature between 20 and 65°C. This experimental value for degradation sensitivity of an organic solar cell allows to translate the encapsulation requirements of the solar cell into a well-defined, objective quantity and allows to predict device lifetimes for different permeation barriers. Furthermore, electroluminescence imaging shows that the degradation is caused solely from a loss of active area caused by water ingress through defects in the aluminum top electrode. For this type of barrier, most of the permeation (>72%) through the aluminum is thus caused by defects with a radius r>0.3µm visible with an optical microscope. Hence, the water ingress through the aluminum top electrode and in turn the lifetime of the organic PV cell can be well predicted by a simple optical inspection.
[Display omitted] .
•Organic solar cells and calcium sensors protected by same barrier: 100nm aluminum.•Calcium sensors can well predict solar cell lifetime—independent of climate.•20mg(H2O)m² degrade 50% of the active area.•>72% of water ingress occurs through large defects (>0.4µm) in aluminum barrier.•Water ingress is predictable by a simple optical inspection of the aluminum barrier. |
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AbstractList | The degradation of non-encapsulated, small-molecule organic solar cells based on ZnPc (zinc phthalocyanine)/C sub(60) with an aluminum top electrode is investigated under different climate conditions and correlated with the water barrier performance of the aluminum electrode layer. The degradation of the solar cells turns out to be dominated by water and can be well predicted by the corrosion of calcium - a sensor for water - under the same conditions. By several independent techniques, an amount of 20 + or - 7 mg(H sub(2)O) m super(-2) is determined to reduce the solar cell efficiency to 50% of the initial value, independent of humidity and temperature between 20 and 65 [degrees]C. This experimental value for degradation sensitivity of an organic solar cell allows to translate the encapsulation requirements of the solar cell into a well-defined, objective quantity and allows to predict device lifetimes for different permeation barriers. Furthermore, electroluminescence imaging shows that the degradation is caused solely from a loss of active area caused by water ingress through defects in the aluminum top electrode. For this type of barrier, most of the permeation (> 72%) through the aluminum is thus caused by defects with a radius r > 0.3 [mu]m visible with an optical microscope. Hence, the water ingress through the aluminum top electrode and in turn the lifetime of the organic PV cell can be well predicted by a simple optical inspection. The degradation of non-encapsulated, small-molecule organic solar cells based on ZnPc (zinc phthalocyanine)/C60 with an aluminum top electrode is investigated under different climate conditions and correlated with the water barrier performance of the aluminum electrode layer. The degradation of the solar cells turns out to be dominated by water and can be well predicted by the corrosion of calcium - a sensor for water - under the same conditions. By several independent techniques, an amount of 20 plus or minus 7 mg(H2O) m-2 is determined to reduce the solar cell efficiency to 50% of the initial value, independent of humidity and temperature between 20 and 65 degree C. This experimental value for degradation sensitivity of an organic solar cell allows to translate the encapsulation requirements of the solar cell into a well-defined, objective quantity and allows to predict device lifetimes for different permeation barriers. Furthermore, electroluminescence imaging shows that the degradation is caused solely from a loss of active area caused by water ingress through defects in the aluminum top electrode. For this type of barrier, most of the permeation (>72%) through the aluminum is thus caused by defects with a radius r>0.3 mu m visible with an optical microscope. Hence, the water ingress through the aluminum top electrode and in turn the lifetime of the organic PV cell can be well predicted by a simple optical inspection. The degradation of non-encapsulated, small-molecule organic solar cells based on ZnPc (zinc phthalocyanine)/C60 with an aluminum top electrode is investigated under different climate conditions and correlated with the water barrier performance of the aluminum electrode layer. The degradation of the solar cells turns out to be dominated by water and can be well predicted by the corrosion of calcium – a sensor for water – under the same conditions. By several independent techniques, an amount of 20±7mg(H2O)m−2 is determined to reduce the solar cell efficiency to 50% of the initial value, independent of humidity and temperature between 20 and 65°C. This experimental value for degradation sensitivity of an organic solar cell allows to translate the encapsulation requirements of the solar cell into a well-defined, objective quantity and allows to predict device lifetimes for different permeation barriers. Furthermore, electroluminescence imaging shows that the degradation is caused solely from a loss of active area caused by water ingress through defects in the aluminum top electrode. For this type of barrier, most of the permeation (>72%) through the aluminum is thus caused by defects with a radius r>0.3µm visible with an optical microscope. Hence, the water ingress through the aluminum top electrode and in turn the lifetime of the organic PV cell can be well predicted by a simple optical inspection. [Display omitted] . •Organic solar cells and calcium sensors protected by same barrier: 100nm aluminum.•Calcium sensors can well predict solar cell lifetime—independent of climate.•20mg(H2O)m² degrade 50% of the active area.•>72% of water ingress occurs through large defects (>0.4µm) in aluminum barrier.•Water ingress is predictable by a simple optical inspection of the aluminum barrier. |
Author | Hermenau, Martin Rösch, Roland Klumbies, Hannes Hoppe, Harald Müller-Meskamp, Lars Karl, Markus Seeland, Marco Leo, Karl |
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Cites_doi | 10.1063/1.3633956 10.1063/1.1626015 10.1063/1.3553864 10.1117/12.510027 10.1016/j.orgel.2011.01.025 10.1016/S0040-6090(02)00584-9 10.1039/C1RA00686J 10.1016/j.solmat.2013.05.013 10.1016/j.solmat.2011.01.035 10.1016/S0141-9382(00)00064-0 10.1016/j.nimb.2006.06.014 10.1021/am800039w 10.1016/j.solmat.2011.01.001 10.1103/PhysRevB.83.165305 10.1016/j.solmat.2011.10.005 10.1007/BF02627216 10.1016/j.solmat.2010.01.006 10.1063/1.3634015 10.1016/j.solmat.2011.09.026 10.1063/1.3590142 10.1016/j.solmat.2007.12.001 10.1039/c2ee03508a 10.1002/adfm.201201592 10.1063/1.4791798 |
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Keywords | Degradation Encapsulation Macro defects Organic solar cells Water permeation barrier Water Performance evaluation Calcium Conversion rate Zinc complex Electroluminescence Photovoltaic cell Optical microscopy Humidity Corrosion test Small molecule Damaging Measurement sensor Permeation Durability Aluminium Imagery Solar cell Sensitivity Corrosion Metallophthalocyanine Fullerenes |
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References | Heliatek GmbH, Heliatek press release from January, (2013). Schubert, Klumbies, Müller-Meskamp, Leo (bib15) 2011; 82 Bin Yang, Song, Gong, Li (bib7) 2010; 94 Meerheim, Olthof, Hermenau, Scholz, Petrich, Tessler (bib14) 2011; 109 Schubert, Hermenau, Meiss, Müller-Meskamp, Leo (bib3) 2012; 22 Paetzold, Winnacker, Henseler, Cesari, Heuser (bib21) 2003; 74 Kumar, Auch, Ou, Ewald, Jin (bib20) 2002; 417 Klumbies, Müller-Meskamp, Mönch, Schubert, Leo (bib23) 2013; 84 Schneider (bib16) 1960; 7 Cros, de Bettignies, Berson, Bailly, Maisse, Lemaitre (bib13) 2011; 95 Rösch, Tanenbaum, Joergensen, Seeland, Bärenklau, Hermenau (bib10) 2012; 5 Burrows, Graff, Gross, Martin, Shi, Hall (bib24) 2001; 22 Hermenau, Riede, Leo, Gevorgyan, Krebs, Norrman (bib9) 2011; 95 Paetzold (bib22) 2004; 5214 Voroshazi, Verreet, Buri, Müller, Di Nuzzo, Heremans (bib8) 2011; 12 Franke, Maennig, Petrich, Pfeiffer (bib2) 2008; 92 Rösch, Krebs, Tanenbaum, Hoppe (bib18) 2012; 97 Kim, Sachse, Hermenau, Fehse, Riede, Mu¨ller-Meskamp (bib4) 2011; 99 Hermenau, Schubert, Klumbies, Fahlteich, Müller-Meskamp, Leo (bib12) 2012; 97 Seeland, Ro¨sch, Hoppe (bib17) 2011; 109 Norrman, Gevorgyan, Krebs (bib25) 2009; 1 Rösch, Eberhardt, Engmann, Gobsch, Hoppe (bib6) 2013; 117 Tanenbaum, Hermenau, Voroshazi, Lloyd, Galagan, Zimmermann (bib11) 2012; 2 Meiss, Hermenau, Tress, Schünemann, Selzer, Hummert (bib5) 2011; 83 Cros, Firon, Lenfant, Trouslard, Beck (bib19) 2006; 251 Rösch (10.1016/j.solmat.2013.10.023_bib10) 2012; 5 Tanenbaum (10.1016/j.solmat.2013.10.023_bib11) 2012; 2 Cros (10.1016/j.solmat.2013.10.023_bib19) 2006; 251 Bin Yang (10.1016/j.solmat.2013.10.023_bib7) 2010; 94 Voroshazi (10.1016/j.solmat.2013.10.023_bib8) 2011; 12 Klumbies (10.1016/j.solmat.2013.10.023_bib23) 2013; 84 Paetzold (10.1016/j.solmat.2013.10.023_bib21) 2003; 74 Kumar (10.1016/j.solmat.2013.10.023_bib20) 2002; 417 Franke (10.1016/j.solmat.2013.10.023_bib2) 2008; 92 Seeland (10.1016/j.solmat.2013.10.023_bib17) 2011; 109 Paetzold (10.1016/j.solmat.2013.10.023_bib22) 2004; 5214 Burrows (10.1016/j.solmat.2013.10.023_bib24) 2001; 22 Kim (10.1016/j.solmat.2013.10.023_bib4) 2011; 99 Schubert (10.1016/j.solmat.2013.10.023_bib15) 2011; 82 Rösch (10.1016/j.solmat.2013.10.023_bib6) 2013; 117 Hermenau (10.1016/j.solmat.2013.10.023_bib9) 2011; 95 10.1016/j.solmat.2013.10.023_bib1 Hermenau (10.1016/j.solmat.2013.10.023_bib12) 2012; 97 Schneider (10.1016/j.solmat.2013.10.023_bib16) 1960; 7 Meiss (10.1016/j.solmat.2013.10.023_bib5) 2011; 83 Schubert (10.1016/j.solmat.2013.10.023_bib3) 2012; 22 Cros (10.1016/j.solmat.2013.10.023_bib13) 2011; 95 Norrman (10.1016/j.solmat.2013.10.023_bib25) 2009; 1 Meerheim (10.1016/j.solmat.2013.10.023_bib14) 2011; 109 Rösch (10.1016/j.solmat.2013.10.023_bib18) 2012; 97 |
References_xml | – volume: 97 start-page: 102 year: 2012 end-page: 108 ident: bib12 article-title: The effect of barrier performance on the lifetime of small-molecule organic solar cells publication-title: Sol. Energy Mater. Sol. Cells contributor: fullname: Leo – volume: 1 start-page: 102 year: 2009 end-page: 112 ident: bib25 article-title: Water-induced degradation of polymer solar cells studied by H2(18)O labeling. publication-title: ACS Appl. Mater. Interfaces contributor: fullname: Krebs – volume: 95 start-page: 1268 year: 2011 end-page: 1277 ident: bib9 article-title: Water and oxygen induced degradation of small molecule organic solar cells publication-title: Sol. Energy Mater. Sol. Cells contributor: fullname: Norrman – volume: 82 start-page: 094101 year: 2011 ident: bib15 article-title: Electrical calcium test for moisture barrier evaluation for organic devices. publication-title: Rev. Sci. Instrum. contributor: fullname: Leo – volume: 99 start-page: 113305 year: 2011 ident: bib4 article-title: Improved efficiency and lifetime in small molecule organic solar cells with optimized conductive polymer electrodes publication-title: Appl. Phys. Lett. contributor: fullname: Mu¨ller-Meskamp – volume: 92 start-page: 732 year: 2008 end-page: 735 ident: bib2 article-title: Long-term stability of tandem solar cells containing small organic molecules publication-title: Sol. Energy Mater. Sol. Cells contributor: fullname: Pfeiffer – volume: 84 start-page: 024103 year: 2013 ident: bib23 article-title: The influence of laterally inhomogeneous corrosion on electrical and optical calcium moisture barrier characterization. publication-title: Rev. Sci. Instrum. contributor: fullname: Leo – volume: 5 start-page: 6521 year: 2012 end-page: 6540 ident: bib10 article-title: Investigation of the degradation mechanisms of a variety of organic photovoltaic devices by combination of imaging techniques—the ISOS-3 inter-laboratory collaboration publication-title: Energy Environ. Sci. contributor: fullname: Hermenau – volume: 251 start-page: 257 year: 2006 end-page: 260 ident: bib19 article-title: Study of thin calcium electrode degradation by ion beam analysis publication-title: Nucl. Instrum. Methods Phys. Res., Sect. B contributor: fullname: Beck – volume: 7 start-page: 269 year: 1960 end-page: 272 ident: bib16 article-title: zur Bestimmung der relativen Luftfeuchtigkeit über gesättigten wässerigen Salzlösungen und wässerigen Schwefelsäurelösungen bei verschiedenen Temperaturen publication-title: Eur. J. Wood Wood Prod. contributor: fullname: Schneider – volume: 117 start-page: 59 year: 2013 end-page: 66 ident: bib6 article-title: Polymer solar cells with enhanced lifetime by improved electrode stability and sealing publication-title: Sol. Energy Mater. Sol. Cells contributor: fullname: Hoppe – volume: 109 start-page: 064513 year: 2011 ident: bib17 article-title: Luminescence imaging of polymer solar cells: Visualization of progressing degradation publication-title: J. Appl. Phys. contributor: fullname: Hoppe – volume: 22 start-page: 4993 year: 2012 end-page: 4999 ident: bib3 article-title: Oxide sandwiched metal thin-film electrodes for long-term stable organic solar cells publication-title: Adv. Funct. Mater. contributor: fullname: Leo – volume: 95 start-page: S65 year: 2011 end-page: S69 ident: bib13 article-title: Definition of encapsulation barrier requirements: a method applied to organic solar cells publication-title: Sol. Energy Mater. Sol. Cells contributor: fullname: Lemaitre – volume: 97 start-page: 176 year: 2012 end-page: 180 ident: bib18 article-title: Quality control of roll-to-roll processed polymer solar modules by complementary imaging methods publication-title: Sol. Energy Mater. Sol. Cells. contributor: fullname: Hoppe – volume: 2 start-page: 882 year: 2012 ident: bib11 article-title: The ISOS-3 inter-laboratory collaboration focused on the stability of a variety of organic photovoltaic devices publication-title: RSC Adv. contributor: fullname: Zimmermann – volume: 22 start-page: 65 year: 2001 end-page: 69 ident: bib24 article-title: Ultra barrier flexible substrates for flat panel displays publication-title: Displays contributor: fullname: Hall – volume: 83 start-page: 165305 year: 2011 ident: bib5 article-title: Tetrapropyl-tetraphenyl-diindenoperylene derivative as a green absorber for high-voltage stable organic solar cells publication-title: Phys. Rev. B: Condens. Matter contributor: fullname: Hummert – volume: 417 start-page: 120 year: 2002 end-page: 126 ident: bib20 article-title: Low moisture permeation measurement through polymer substrates for organic light emitting devices publication-title: Thin Solid Films. contributor: fullname: Jin – volume: 12 start-page: 736 year: 2011 end-page: 744 ident: bib8 article-title: Influence of cathode oxidation via the hole extraction layer in polymer:fullerene solar cells publication-title: Org. Electron.. contributor: fullname: Heremans – volume: 74 start-page: 5147 year: 2003 ident: bib21 article-title: Permeation rate measurements by electrical analysis of calcium corrosion publication-title: Rev. Sci. Instrum. contributor: fullname: Heuser – volume: 109 start-page: 103102 year: 2011 ident: bib14 article-title: Investigation of C60F36 as low-volatility p-dopant in organic optoelectronic devices publication-title: J. Appl. Phys. contributor: fullname: Tessler – volume: 94 start-page: 846 year: 2010 end-page: 849 ident: bib7 article-title: The degradation of indium tin oxide/pentacene/fullerene/tris-8-hydroxy-quinolinato aluminum/aluminum heterojunction organic solar cells: by oxygen or moisture? publication-title: Sol. Energy Mater. Sol. Cells contributor: fullname: Li – volume: 5214 start-page: 73 year: 2004 end-page: 82 ident: bib22 article-title: High-sensitivity permeation measurements on flexible OLED substrates publication-title: Proc. SPIE contributor: fullname: Paetzold – volume: 82 start-page: 094101 year: 2011 ident: 10.1016/j.solmat.2013.10.023_bib15 article-title: Electrical calcium test for moisture barrier evaluation for organic devices. publication-title: Rev. Sci. Instrum. doi: 10.1063/1.3633956 contributor: fullname: Schubert – volume: 74 start-page: 5147 year: 2003 ident: 10.1016/j.solmat.2013.10.023_bib21 article-title: Permeation rate measurements by electrical analysis of calcium corrosion publication-title: Rev. Sci. Instrum. doi: 10.1063/1.1626015 contributor: fullname: Paetzold – volume: 109 start-page: 064513 year: 2011 ident: 10.1016/j.solmat.2013.10.023_bib17 article-title: Luminescence imaging of polymer solar cells: Visualization of progressing degradation publication-title: J. Appl. Phys. doi: 10.1063/1.3553864 contributor: fullname: Seeland – volume: 5214 start-page: 73 year: 2004 ident: 10.1016/j.solmat.2013.10.023_bib22 article-title: High-sensitivity permeation measurements on flexible OLED substrates publication-title: Proc. SPIE doi: 10.1117/12.510027 contributor: fullname: Paetzold – volume: 12 start-page: 736 year: 2011 ident: 10.1016/j.solmat.2013.10.023_bib8 article-title: Influence of cathode oxidation via the hole extraction layer in polymer:fullerene solar cells publication-title: Org. Electron.. doi: 10.1016/j.orgel.2011.01.025 contributor: fullname: Voroshazi – volume: 417 start-page: 120 year: 2002 ident: 10.1016/j.solmat.2013.10.023_bib20 article-title: Low moisture permeation measurement through polymer substrates for organic light emitting devices publication-title: Thin Solid Films. doi: 10.1016/S0040-6090(02)00584-9 contributor: fullname: Kumar – volume: 2 start-page: 882 year: 2012 ident: 10.1016/j.solmat.2013.10.023_bib11 article-title: The ISOS-3 inter-laboratory collaboration focused on the stability of a variety of organic photovoltaic devices publication-title: RSC Adv. doi: 10.1039/C1RA00686J contributor: fullname: Tanenbaum – volume: 117 start-page: 59 year: 2013 ident: 10.1016/j.solmat.2013.10.023_bib6 article-title: Polymer solar cells with enhanced lifetime by improved electrode stability and sealing publication-title: Sol. Energy Mater. Sol. Cells doi: 10.1016/j.solmat.2013.05.013 contributor: fullname: Rösch – volume: 95 start-page: S65 year: 2011 ident: 10.1016/j.solmat.2013.10.023_bib13 article-title: Definition of encapsulation barrier requirements: a method applied to organic solar cells publication-title: Sol. Energy Mater. Sol. Cells doi: 10.1016/j.solmat.2011.01.035 contributor: fullname: Cros – volume: 22 start-page: 65 year: 2001 ident: 10.1016/j.solmat.2013.10.023_bib24 article-title: Ultra barrier flexible substrates for flat panel displays publication-title: Displays doi: 10.1016/S0141-9382(00)00064-0 contributor: fullname: Burrows – volume: 251 start-page: 257 year: 2006 ident: 10.1016/j.solmat.2013.10.023_bib19 article-title: Study of thin calcium electrode degradation by ion beam analysis publication-title: Nucl. Instrum. Methods Phys. Res., Sect. B doi: 10.1016/j.nimb.2006.06.014 contributor: fullname: Cros – volume: 1 start-page: 102 year: 2009 ident: 10.1016/j.solmat.2013.10.023_bib25 article-title: Water-induced degradation of polymer solar cells studied by H2(18)O labeling. publication-title: ACS Appl. Mater. Interfaces doi: 10.1021/am800039w contributor: fullname: Norrman – volume: 95 start-page: 1268 year: 2011 ident: 10.1016/j.solmat.2013.10.023_bib9 article-title: Water and oxygen induced degradation of small molecule organic solar cells publication-title: Sol. Energy Mater. Sol. Cells doi: 10.1016/j.solmat.2011.01.001 contributor: fullname: Hermenau – volume: 83 start-page: 165305 year: 2011 ident: 10.1016/j.solmat.2013.10.023_bib5 article-title: Tetrapropyl-tetraphenyl-diindenoperylene derivative as a green absorber for high-voltage stable organic solar cells publication-title: Phys. Rev. B: Condens. Matter doi: 10.1103/PhysRevB.83.165305 contributor: fullname: Meiss – volume: 97 start-page: 176 year: 2012 ident: 10.1016/j.solmat.2013.10.023_bib18 article-title: Quality control of roll-to-roll processed polymer solar modules by complementary imaging methods publication-title: Sol. Energy Mater. Sol. Cells. doi: 10.1016/j.solmat.2011.10.005 contributor: fullname: Rösch – volume: 7 start-page: 269 year: 1960 ident: 10.1016/j.solmat.2013.10.023_bib16 article-title: zur Bestimmung der relativen Luftfeuchtigkeit über gesättigten wässerigen Salzlösungen und wässerigen Schwefelsäurelösungen bei verschiedenen Temperaturen publication-title: Eur. J. Wood Wood Prod. doi: 10.1007/BF02627216 contributor: fullname: Schneider – volume: 94 start-page: 846 year: 2010 ident: 10.1016/j.solmat.2013.10.023_bib7 article-title: The degradation of indium tin oxide/pentacene/fullerene/tris-8-hydroxy-quinolinato aluminum/aluminum heterojunction organic solar cells: by oxygen or moisture? publication-title: Sol. Energy Mater. Sol. Cells doi: 10.1016/j.solmat.2010.01.006 contributor: fullname: Bin Yang – ident: 10.1016/j.solmat.2013.10.023_bib1 – volume: 99 start-page: 113305 year: 2011 ident: 10.1016/j.solmat.2013.10.023_bib4 article-title: Improved efficiency and lifetime in small molecule organic solar cells with optimized conductive polymer electrodes publication-title: Appl. Phys. Lett. doi: 10.1063/1.3634015 contributor: fullname: Kim – volume: 97 start-page: 102 year: 2012 ident: 10.1016/j.solmat.2013.10.023_bib12 article-title: The effect of barrier performance on the lifetime of small-molecule organic solar cells publication-title: Sol. Energy Mater. Sol. Cells doi: 10.1016/j.solmat.2011.09.026 contributor: fullname: Hermenau – volume: 109 start-page: 103102 year: 2011 ident: 10.1016/j.solmat.2013.10.023_bib14 article-title: Investigation of C60F36 as low-volatility p-dopant in organic optoelectronic devices publication-title: J. Appl. Phys. doi: 10.1063/1.3590142 contributor: fullname: Meerheim – volume: 92 start-page: 732 year: 2008 ident: 10.1016/j.solmat.2013.10.023_bib2 article-title: Long-term stability of tandem solar cells containing small organic molecules publication-title: Sol. Energy Mater. Sol. Cells doi: 10.1016/j.solmat.2007.12.001 contributor: fullname: Franke – volume: 5 start-page: 6521 year: 2012 ident: 10.1016/j.solmat.2013.10.023_bib10 article-title: Investigation of the degradation mechanisms of a variety of organic photovoltaic devices by combination of imaging techniques—the ISOS-3 inter-laboratory collaboration publication-title: Energy Environ. Sci. doi: 10.1039/c2ee03508a contributor: fullname: Rösch – volume: 22 start-page: 4993 year: 2012 ident: 10.1016/j.solmat.2013.10.023_bib3 article-title: Oxide sandwiched metal thin-film electrodes for long-term stable organic solar cells publication-title: Adv. Funct. Mater. doi: 10.1002/adfm.201201592 contributor: fullname: Schubert – volume: 84 start-page: 024103 year: 2013 ident: 10.1016/j.solmat.2013.10.023_bib23 article-title: The influence of laterally inhomogeneous corrosion on electrical and optical calcium moisture barrier characterization. publication-title: Rev. Sci. Instrum. doi: 10.1063/1.4791798 contributor: fullname: Klumbies |
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Snippet | The degradation of non-encapsulated, small-molecule organic solar cells based on ZnPc (zinc phthalocyanine)/C60 with an aluminum top electrode is investigated... The degradation of non-encapsulated, small-molecule organic solar cells based on ZnPc (zinc phthalocyanine)/C sub(60) with an aluminum top electrode is... |
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SubjectTerms | Aluminum base alloys Applied sciences Barriers Degradation Direct energy conversion and energy accumulation Electrical engineering. Electrical power engineering Electrical power engineering Electrodes Encapsulation Energy Exact sciences and technology Fullerenes Macro defects Natural energy Organic solar cells Permeation Photoelectric conversion Photovoltaic cells Photovoltaic conversion Solar cells Solar cells. Photoelectrochemical cells Solar energy Water permeation barrier |
Title | Water ingress into and climate dependent lifetime of organic photovoltaic cells investigated by calcium corrosion tests |
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