Manganese‐Catalyzed Hydrosilylation Reactions

Over the past few decades, manganese‐catalyzed hydrosilylation of C=O or C=C/C≡C unsaturated bonds have undergone enormous developments. In this focus review, the hydrosilylation reactions of alkenes, alkynes, and carbonyl‐containing substrates catalyzed by manganese complexes are summarized. Moreov...

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Published inChemistry, an Asian journal Vol. 13; no. 17; pp. 2307 - 2315
Main Authors Yang, Xiaoxu, Wang, Congyang
Format Journal Article
LanguageEnglish
Published Germany Wiley Subscription Services, Inc 04.09.2018
Subjects
Alkenes
Alkynes
carbonyl bonds
Carbonyls
Chemical reactions
Chemistry
Hydrosilylation
Manganese
Substrates
hydrosilylation
alkenes
carbonyl bonds
manganese
alkynes
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Summary:Over the past few decades, manganese‐catalyzed hydrosilylation of C=O or C=C/C≡C unsaturated bonds have undergone enormous developments. In this focus review, the hydrosilylation reactions of alkenes, alkynes, and carbonyl‐containing substrates catalyzed by manganese complexes are summarized. Moreover, the mechanisms of the manganese‐catalyzed hydrosilylation are briefly discussed. Causing a reaction: The manganese‐catalyzed hydrosilylation of alkenes, alkynes, and carbonyl‐containing substrates has developed extensively in recent years. In this focus review, hydrosilylation reactions mediated by manganese catalysts are summarized and the underlying mechanisms are discussed (see scheme).
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ISSN:1861-4728
1861-471X
1861-471X
DOI:10.1002/asia.201800618