N‐Centered Radical Directed Remote C−H Bond Functionalization via Hydrogen Atom Transfer
The N‐centered radical directed remote C−H bond functionalization via hydrogen‐atom‐transfer at distant sites has developed as an enormous potential tool for the organic synthetic chemists. Unactivated and remote secondary and tertiary, as well as selected primary C−H bonds, can be utilized for func...
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| Published in | Chemistry, an Asian journal Vol. 15; no. 6; pp. 651 - 672 |
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| Main Authors | , , |
| Format | Journal Article |
| Language | English |
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16.03.2020
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| Abstract | The N‐centered radical directed remote C−H bond functionalization via hydrogen‐atom‐transfer at distant sites has developed as an enormous potential tool for the organic synthetic chemists. Unactivated and remote secondary and tertiary, as well as selected primary C−H bonds, can be utilized for functionalization by following these methodologies. The synthesis of the heterocyclic scaffolds provides them extra attention for the modern days′ developments in this field of unactivated remote C−H bonds functionalizations.
Not so far: This minireview summarizes the progress on the N‐centered radical‐mediated remote C−H bond functionalization via HAT, towards the sustainable synthesis of N‐containing important motifs and heterocycles. |
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| AbstractList | Abstract
The N‐centered radical directed remote C−H bond functionalization via hydrogen‐atom‐transfer at distant sites has developed as an enormous potential tool for the organic synthetic chemists. Unactivated and remote secondary and tertiary, as well as selected primary C−H bonds, can be utilized for functionalization by following these methodologies. The synthesis of the heterocyclic scaffolds provides them extra attention for the modern days′ developments in this field of unactivated remote C−H bonds functionalizations. The N‐centered radical directed remote C−H bond functionalization via hydrogen‐atom‐transfer at distant sites has developed as an enormous potential tool for the organic synthetic chemists. Unactivated and remote secondary and tertiary, as well as selected primary C−H bonds, can be utilized for functionalization by following these methodologies. The synthesis of the heterocyclic scaffolds provides them extra attention for the modern days′ developments in this field of unactivated remote C−H bonds functionalizations. Not so far: This minireview summarizes the progress on the N‐centered radical‐mediated remote C−H bond functionalization via HAT, towards the sustainable synthesis of N‐containing important motifs and heterocycles. The N‐centered radical directed remote C−H bond functionalization via hydrogen‐atom‐transfer at distant sites has developed as an enormous potential tool for the organic synthetic chemists. Unactivated and remote secondary and tertiary, as well as selected primary C−H bonds, can be utilized for functionalization by following these methodologies. The synthesis of the heterocyclic scaffolds provides them extra attention for the modern days′ developments in this field of unactivated remote C−H bonds functionalizations. The N-centered radical directed remote C-H bond functionalization via hydrogen-atom-transfer at distant sites has developed as an enormous potential tool for the organic synthetic chemists. Unactivated and remote secondary and tertiary, as well as selected primary C-H bonds, can be utilized for functionalization by following these methodologies. The synthesis of the heterocyclic scaffolds provides them extra attention for the modern days' developments in this field of unactivated remote C-H bonds functionalizations. |
| Author | Kumar, Gautam Pradhan, Suman Chatterjee, Indranil |
| Author_xml | – sequence: 1 givenname: Gautam surname: Kumar fullname: Kumar, Gautam organization: Indian Institute of Technology Ropar – sequence: 2 givenname: Suman surname: Pradhan fullname: Pradhan, Suman organization: Indian Institute of Technology Ropar – sequence: 3 givenname: Indranil orcidid: 0000-0001-8957-5182 surname: Chatterjee fullname: Chatterjee, Indranil email: indranil.chatterjee@iitrpr.ac.in organization: Indian Institute of Technology Ropar |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/32011095$$D View this record in MEDLINE/PubMed |
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| Copyright | 2020 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim 2020 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. |
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| Keywords | C−N/C−C bond formation heterocycles hydrogen atom transfer N-centered radical remote functionalization |
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| Snippet | The N‐centered radical directed remote C−H bond functionalization via hydrogen‐atom‐transfer at distant sites has developed as an enormous potential tool for... The N-centered radical directed remote C-H bond functionalization via hydrogen-atom-transfer at distant sites has developed as an enormous potential tool for... Abstract The N‐centered radical directed remote C−H bond functionalization via hydrogen‐atom‐transfer at distant sites has developed as an enormous potential... |
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| SubjectTerms | Chemistry Chemists C−N/C−C bond formation heterocycles hydrogen atom transfer Hydrogen bonds N-centered radical remote functionalization |
| Title | N‐Centered Radical Directed Remote C−H Bond Functionalization via Hydrogen Atom Transfer |
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