N‐Centered Radical Directed Remote C−H Bond Functionalization via Hydrogen Atom Transfer

The N‐centered radical directed remote C−H bond functionalization via hydrogen‐atom‐transfer at distant sites has developed as an enormous potential tool for the organic synthetic chemists. Unactivated and remote secondary and tertiary, as well as selected primary C−H bonds, can be utilized for func...

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Bibliographic Details
Published inChemistry, an Asian journal Vol. 15; no. 6; pp. 651 - 672
Main Authors Kumar, Gautam, Pradhan, Suman, Chatterjee, Indranil
Format Journal Article
LanguageEnglish
Published Germany Wiley Subscription Services, Inc 16.03.2020
Subjects
Chemistry
Chemists
C−N/C−C bond formation
heterocycles
hydrogen atom transfer
Hydrogen bonds
N-centered radical
remote functionalization
C−N/C−C bond formation
heterocycles
hydrogen atom transfer
N-centered radical
remote functionalization
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Summary:The N‐centered radical directed remote C−H bond functionalization via hydrogen‐atom‐transfer at distant sites has developed as an enormous potential tool for the organic synthetic chemists. Unactivated and remote secondary and tertiary, as well as selected primary C−H bonds, can be utilized for functionalization by following these methodologies. The synthesis of the heterocyclic scaffolds provides them extra attention for the modern days′ developments in this field of unactivated remote C−H bonds functionalizations. Not so far: This minireview summarizes the progress on the N‐centered radical‐mediated remote C−H bond functionalization via HAT, towards the sustainable synthesis of N‐containing important motifs and heterocycles.
Bibliography:ObjectType-Article-2
SourceType-Scholarly Journals-1
ObjectType-Feature-3
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ObjectType-Review-1
ISSN:1861-4728
1861-471X
DOI:10.1002/asia.201901744