The Redox Journey of Iconic Ferrocene: Ferrocenium Dications and Ferrocenate Anions

The recent discoveries of both dicationic and monoanionic ferrocene derivatives throw light on the effect of the substituents on the C5 ring as well as the choice of redox agents and solvent system in the preparation of previously believed to be difficult synthetic targets. These oxidized and reduce...

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Bibliographic Details
Published inAngewandte Chemie International Edition Vol. 60; no. 23; pp. 12632 - 12635
Main Authors Walawalkar, Mrinalini G., Pandey, Priya, Murugavel, Ramaswamy
Format Journal Article
LanguageEnglish
Published Germany Wiley Subscription Services, Inc 01.06.2021
EditionInternational ed. in English
Subjects
Anions
electrochemistry
ferrocenate
ferrocene
organometallic chemistry
redox chemistry
ferrocenate
electrochemistry
ferrocene
organometallic chemistry
redox chemistry
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Summary:The recent discoveries of both dicationic and monoanionic ferrocene derivatives throw light on the effect of the substituents on the C5 ring as well as the choice of redox agents and solvent system in the preparation of previously believed to be difficult synthetic targets. These oxidized and reduced forms of ferrocene are of interest to spectroscopists, magnetochemists, and theoreticians.
Bibliography:ObjectType-Article-2
SourceType-Scholarly Journals-1
ObjectType-Feature-3
content type line 23
ObjectType-Review-1
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.202101770