Mizoroki-Heck-Type Reaction Mediated by Potassium tert-Butoxide

In the absence of transition‐metal catalysts, a Mizoroki–Heck‐type reaction proceeded to give stilbene derivatives in a simple manner using an aryl halide, a styrene derivative, KOtBu, EtOH, and DMF (see scheme; DMF=N,N‐dimethylformamide).

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Bibliographic Details
Published inAngewandte Chemie (International ed.) Vol. 50; no. 20; pp. 4671 - 4674
Main Authors Shirakawa, Eiji, Zhang, Xuejing, Hayashi, Tamio
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag 09.05.2011
WILEY‐VCH Verlag
Wiley
Wiley Subscription Services, Inc
EditionInternational ed. in English
Subjects
alkenes
aryl radicals
Butanols - chemistry
Chemistry
Chemistry, Multidisciplinary
CC coupling
Molecular Structure
Physical Sciences
Science & Technology
single-electron transfer
Stereoisomerism
Styrene - chemical synthesis
Styrene - chemistry
synthetic methods
Toluene - analogs & derivatives
Toluene - chemistry
C-C coupling
HALIDES
SINGLE ELECTRON-TRANSFER
REDUCTION
HYDROCARBONS
ALKOXIDES
aryl radicals
ARYLATION
single-electron transfer
alkenes
synthetic methods
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Summary:In the absence of transition‐metal catalysts, a Mizoroki–Heck‐type reaction proceeded to give stilbene derivatives in a simple manner using an aryl halide, a styrene derivative, KOtBu, EtOH, and DMF (see scheme; DMF=N,N‐dimethylformamide).
Bibliography:ark:/67375/WNG-TBW3CTWH-D
This work was supported financially by a Grant-in-Aid for Scientific Research (the Global COE Program "Integrated Materials Science" on Kyoto University) from Ministry of Education, Culture, Sports, Science and Technology (Japan). We are grateful to Ms. Yuki Yamamoto, Dr. Kenji Kitayama, and Mr. Ikuo Takahashi (Daicel Chemical Industries, Ltd.) for ICP analysis. We thank Dr. Kazufumi Kohno (Tokyo University of Agriculture and Technology) for carrying out duplicate experiments.
Ministry of Education, Culture, Sports, Science and Technology (Japan)
istex:25B6FCB65ABB8D342F4BD05DA25FFE4EC9025596
ArticleID:ANIE201008220
This work was supported financially by a Grant‐in‐Aid for Scientific Research (the Global COE Program “Integrated Materials Science” on Kyoto University) from Ministry of Education, Culture, Sports, Science and Technology (Japan). We are grateful to Ms. Yuki Yamamoto, Dr. Kenji Kitayama, and Mr. Ikuo Takahashi (Daicel Chemical Industries, Ltd.) for ICP analysis. We thank Dr. Kazufumi Kohno (Tokyo University of Agriculture and Technology) for carrying out duplicate experiments.
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201008220