Dynamic self-correcting nucleophilic aromatic substitution

• Published in: Nature chemistry Vol. 10; no. 10; pp. 1023 - 1030
• Main Authors: Ong, Wen Jie, Swager, Timothy M.
• Format: Journal Article
• Language: English
• Published: London Nature Publishing Group UK 01.10.2018; Springer Nature; Nature Publishing Group
• Subjects: 639/638/403/933; 639/638/549/933; 639/925; Analytical Chemistry; Biochemistry; Chemical synthesis; Chemistry; Chemistry and Materials Science; Chemistry, Multidisciplinary; Chemistry/Food Science; Inorganic Chemistry; Organic Chemistry; Physical Chemistry; Physical Sciences; Polymers; Regioselectivity; Science & Technology; Substitution reactions; POLYMER NETWORKS; ROUTE; COVALENT CHEMISTRY; BONDS; SYSTEMS; CAGES; SINGLE-STEP SYNTHESIS; METATHESIS

Dynamic covalent chemistry, with its ability to correct synthetic dead-ends, allows for the synthesis of elaborate extended network materials in high yields. However, the limited number of reactions amenable to dynamic covalent chemistry necessarily confines the scope and functionality of materials...