Methylpalladium complexes with pyrimidine-functionalized N-heterocyclic carbene ligands

A series of methylpalladium(II) complexes with pyrimidine-NHC ligands carrying different aryl- and alkyl substituents R ([((pym)^(NHC-R))Pd(II)(CH3)X] with X = Cl, CF3COO, CH3) has been prepared by transmetalation reactions from the corresponding silver complexes and chloro(methyl)(cyclooctadiene)pa...

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Bibliographic Details
Published inBeilstein journal of organic chemistry Vol. 12; no. 1; pp. 1557 - 1565
Main Authors Meyer, Dirk, Strassner, Thomas
Format Journal Article
LanguageEnglish
Published Germany Beilstein-Institut zur Föerderung der Chemischen Wissenschaften 21.07.2016
Beilstein-Institut
Subjects
alkane activation
alkyl complex
Chemistry
Full Research Paper
NHC
palladium
solid state structure
NHC
palladium
alkyl complex
solid state structure
alkane activation
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Summary:A series of methylpalladium(II) complexes with pyrimidine-NHC ligands carrying different aryl- and alkyl substituents R ([((pym)^(NHC-R))Pd(II)(CH3)X] with X = Cl, CF3COO, CH3) has been prepared by transmetalation reactions from the corresponding silver complexes and chloro(methyl)(cyclooctadiene)palladium(II). The dimethyl(1-(2-pyrimidyl)-3-(2,6-diisopropylphenyl)imidazolin-2-ylidene)palladium(II) complex was synthesized via the free carbene route. All complexes were fully characterized by standard methods and in three cases also by a solid state structure.
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ISSN:1860-5397
2195-951X
1860-5397
DOI:10.3762/bjoc.12.150