High-Resolution Dipolar n.m.r. Spectra in Solids

Recent advances in solid state n.m.r. spectroscopy permit obervation of high-resolution dipolar spectra, and thus renewed consideration can be given to solid state n.m.r. as a tool for determining molecular structure. This is illustrated with $^{13}$C and $^{14}$N single-crystal spectra obtained wit...

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Published inPhilosophical transactions of the Royal Society of London. Series A: Mathematical, physical, and engineering sciences Vol. 299; no. 1452; p. 547
Main Authors R. G. Griffin, G. Bodenhausen, R. A. Haberkorn, T. H. Huang, M. Munowitz, R. Osredkar, D. J. Ruben, R. E. Stark, H. Van Willigen
Format Journal Article
LanguageEnglish
Published The Royal Society 18.03.1981
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Summary:Recent advances in solid state n.m.r. spectroscopy permit obervation of high-resolution dipolar spectra, and thus renewed consideration can be given to solid state n.m.r. as a tool for determining molecular structure. This is illustrated with $^{13}$C and $^{14}$N single-crystal spectra obtained with both one- and two-dimensional n.m.r. techniques. The successful observation of these spectra is due to the fact that many dipolar interactions are inhomogeneous, and for this reason it is also possible to obtain high-resolution dipolar spectra from powder samples. Methods that accomplish this goal are described and illustrated with $^{13}$C-$^{1}$H dipolar spectra.
ISSN:1364-503X
1471-2962
DOI:10.1098/rsta.1981.0034