Exploring the Implementation of GaAsBi Alloys as Strain-Reducing Layers in InAs/GaAs Quantum Dots

• Published in: Nanomaterials (Basel, Switzerland) Vol. 14; no. 4; p. 375
• Main Authors: Braza, Verónica, Fernández, Daniel, Ben, Teresa, Flores, Sara, Bailey, Nicholas James, Carr, Matthew, Richards, Robert, Gonzalez, David
• Format: Journal Article
• Language: English
• Published: Switzerland MDPI AG 17.02.2024; MDPI
• Subjects: Alloys; Bismuth; Capping; Chemical properties; Decomposition; Dislocation density; GaAsBi capping; Gallium arsenide; Indium arsenides; Low temperature; Molecular beam epitaxy; Nanoparticles; Nanotechnology; Nanowires; Photovoltaic cells; Quantum dots; Reduction; self-assembled InAs QDs; Spectrum analysis; STEM compositional analyses; Structure; Temperature; Thermal properties; Thickness; Threading dislocations; Spain; United States > US; STEM compositional analyses; GaAsBi capping; self-assembled InAs QDs
• ISSN: 2079-4991; 2079-4991
• DOI: 10.3390/nano14040375

This paper investigates the effect of GaAsBi strain reduction layers (SRLs) on InAs QDs with different Bi fluxes to achieve nanostructures with improved temperature stability. The SRLs are grown at a lower temperature (370 °C) than the usual capping temperature for InAs QDs (510 °C). The study finds that GaAs capping at low temperatures reduces QD decomposition and leads to larger pyramidal dots but also increases the threading dislocation (TD) density. When adding Bi to the capping layer, a significant reduction in TD density is observed, but unexpected structural changes also occur. Increasing the Bi flux does not increase the Bi content but rather the layer thickness. The maximum Bi content for all layers is 2.4%. A higher Bi flux causes earlier Bi incorporation, along with the formation of an additional InGaAs layer above the GaAsBi layer due to In segregation from QD erosion. Additionally, the implementation of GaAsBi SRLs results in smaller dots due to enhanced QD decomposition, which is contrary to the expected function of an SRL. No droplets were detected on the surface of any sample, but we did observe regions of horizontal nanowires within the epilayers for the Bi-rich samples, indicating nanoparticle formation.