Optically active dithiophosphoric acid, its ammonium salt, and S-esters on the basis of (1R)-endo-(+)-fenchyl alcohol

Optically active dithiophosphoric acid was prepared by the reaction of tetraphosphorus decasulfide with (1R)-endo-(+)-fenchyl alcohol. The ammonium salt of dithiophosphoric acid prepared reacts with methyl chloroacetate and benzoyl chloride to give dithiophosphate S-esters.

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Bibliographic Details
Published inPhosphorus, sulfur, and silicon and the related elements Vol. 189; no. 9; pp. 1354 - 1360
Main Authors Nizamov, Ilyas S., Gabdullina, Gulnara T., Terenzhev, Dmitriy A., Nurmukhametov, Almaz R., Nizamov, Ilnar D., Cherkasov, Rafael A.
Format Journal Article
LanguageEnglish
Published ABINGDON Taylor & Francis 02.09.2014
Taylor & Francis Ltd
Subjects
(1R)-endo-(+)-fenchyl alcohol
Acids
Alcohol
benzoyl chloride
Chemistry
Chemistry, Inorganic & Nuclear
Chemistry, Organic
dithiophosphate S-esters
dithiophosphoric acid
methyl chloroacetate
Physical Sciences
Science & Technology
Tetraphosphorus decasulfide
Tetraphosphorus decasulfide
dithiophosphoric acid
ALKYLENE DITHIOPHOSPHATES
dithiophosphate S-esters
ANALOGS
PYROPHOSPHATE
ORGANIC DERIVATIVES
H-PHOSPHONATES
(1R)-endo-(+)-fenchyl alcohol
methyl chloroacetate
benzoyl chloride
EFFICIENT
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Summary:Optically active dithiophosphoric acid was prepared by the reaction of tetraphosphorus decasulfide with (1R)-endo-(+)-fenchyl alcohol. The ammonium salt of dithiophosphoric acid prepared reacts with methyl chloroacetate and benzoyl chloride to give dithiophosphate S-esters.
ISSN:1042-6507
1563-5325
DOI:10.1080/10426507.2013.860531