Simple model for the electric field and spatial distribution of ions in a microdroplet

It is well established that the chemistry in microdroplets has been found to be radically different from reactions in bulk, particularly in the case of water. It has also been established that there is a threshold size for microdroplets to behave differently than droplets near the 10 µm diameter ran...

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Published inThe Journal of chemical physics Vol. 152; no. 18; pp. 184702 - 184711
Main Authors Chamberlayne, Christian F., Zare, Richard N.
Format Journal Article
LanguageEnglish
Published United States American Institute of Physics 14.05.2020
AIP Publishing LLC
Subjects
Acceleration
Conducting fluids
Diameters
Droplets
Electric fields
Spatial distribution
Three dimensional models
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Summary:It is well established that the chemistry in microdroplets has been found to be radically different from reactions in bulk, particularly in the case of water. It has also been established that there is a threshold size for microdroplets to behave differently than droplets near the 10 µm diameter range. We present a three-dimensional electrostatic treatment in the spirit of the Gouy–Chapman model for double layers at interfaces. Our treatment predicts a strong concentration of charged molecules toward the surface of the droplet. As the droplet size deceases, the majority of the volume of the liquid experiences a large DC electric field. Such electric fields are highly unusual in a conducting fluid such as water. We believe that this unique environment helps to explain the reaction rate acceleration and new chemistry that have been observed in microdroplets compared to bulk phase.
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ISSN:0021-9606
1089-7690
1089-7690
DOI:10.1063/5.0006550