Synthesis of Tungsten-Doped Vanadium Dioxide Using a Modified Polyol Method Involving 1-Dodecanol

• Published in: Materials Vol. 13; no. 23; p. 5384
• Main Authors: Lee, Yonghyun, Jung, Sang Won, Park, Sang Hwi, Yoo, Jung Whan, Park, Juhyun
• Format: Journal Article
• Language: English
• Published: Switzerland MDPI AG 27.11.2020; MDPI
• Subjects: Atmospheric pressure; Chemical vapor deposition; Crystal defects; Crystal structure; Dispersion; Dodecanol; Doping; Ethanol; Ethylene glycol; Insulators; Metal-insulator transition; Methods; Mixing ratio; nanoparticles; Oligomerization; smart windows; Spectrum analysis; thermochromic; Transition temperature; Tungsten; tungsten doping; Vanadium dioxide; vanadium oxide; Vanadium oxides; X ray powder diffraction; United States > US; thermochromic; tungsten doping; nanoparticles; vanadium oxide; smart windows
• ISSN: 1996-1944; 1996-1944
• DOI: 10.3390/ma13235384

The doping of tungsten into VO (M) via a polyol process that is based on oligomerization of ammonium metavanadate and ethylene glycol (EG) to synthesize a vanadyl ethylene glycolate (VEG) followed by postcalcination was carried out by simply adding 1-dodecanol and the tungsten source tungstenoxytetrachloride (WOCl ). Tungsten-doped VEGs (W-VEGs) and their calcinated compounds (W VO ) were prepared with varying mixing ratios of EG to 1-dodecanol and WOCl concentrations. Characterizations of W-VEGs by powder X-ray diffraction, differential scanning calorimetry, scanning electron microscopy, and infrared and transmittance spectroscopy showed that tungsten elements were successfully doped into W VO , thereby decreasing the metal-insulator transition temperature from 68 down to 51 °C. Our results suggested that WOCl variously combined with 1-dodecanol might interrupt the linear growth of W-VEGs, but that such an interruption might be alleviated at the optimal 1:1 mixing ratio of EG to 1-dodecanol, resulting in the successful W doping. The difference in the solar modulations of a W VO dispersion measured at 20 and 70 °C was increased to 21.8% while that of a pure VO dispersion was 2.5%. It was suggested that WOCl coupled with both EG and 1-dodecanol at an optimal mixing ratio could improve the formation of W-VEG and W VO and that the bulky dodecyl chains might act as defects to decrease crystallinity.