Performance of PATC-PDMDAAC Composite Coagulants in Low-Temperature and Low-Turbidity Water Treatment

• Published in: Materials Vol. 12; no. 17; p. 2824
• Main Authors: Zhang, Peng, Liao, Lina, Zhu, Guocheng
• Format: Journal Article
• Language: English
• Published: Switzerland MDPI AG 02.09.2019; MDPI
• Subjects: Adsorption; aluminium chloride; Aqueous solutions; Chemical reactions; Chloride; Chlorides; Coagulants; Coagulation; composite flocculant; Differential scanning calorimetry; Dosage; Efficiency; Flocculation; Fluorescence; Fourier transforms; Functional groups; Infrared analysis; Infrared spectroscopy; Laboratories; Low temperature; low turbidity; Molecular weight; Monomers; Organic carbon; Pollutants; poly(diallyldimethylammonium chloride); Polymerization; Polymers; Reagents; Salt; Spectroscopic analysis; Thermal stability; Thermogravimetric analysis; Titanium; titanium tetrachloride; Turbidity; Viscosity; Water treatment; Zeta potential; Beijing China; United States > US; China; Japan; Germany; composite flocculant; low turbidity; titanium tetrachloride; low temperature; aluminium chloride; poly(diallyldimethylammonium chloride)
• ISSN: 1996-1944; 1996-1944
• DOI: 10.3390/ma12172824

A novel composite was synthesized by using flocculant polyaluminum titanium silicate chloride (PATC) and poly(diallyldimethylammonium chloride) (PDMDAAC) monomers to treat low-temperature and low-turbidity water. The structure and physicochemical properties of PATC-PDMDAAC were analyzed by Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis/differential scanning calorimetry (TG/DSC), X-ray diffraction spectroscopy (XRD), and scanning electron microscopy-energy dispersion spectrum (SEM-EDS). The compound flocculant produced new functional groups exhibiting great thermal stability, and the complex chemical reaction between the two monomers generated new substances with reticular structures. Coagulation performance results showed that the PATC-PDMDAAC had an organic and inorganic ratio of 0.15 and exhibited excellent removal efficiency at pH 9.0, dosage of 1.80 mg/L, sedimentation time of 40 min, and a stirring speed of 110 r/min. The optimal treatment efficiency reduced the turbidity to 0.56 NTU (Nephelometric Turbidity Unit). The removal rates of TOC (Total Organic Carbon) and UV254 (Ultraviolet 254) were 62.18% (from 7.23 mg/L to 2.734 mg/L) and 99.99% (from 10 mg/L to 0.001 mg/L). The 3D fluorescence, zeta potential and kinetic analysis in the flocculation process indicated that coagulant electroneutralization and adsorption bridge in a slightly alkaline environment played a dominant role, and a sufficient and effective collision occurred between the coagulant and particulate matter under the optimal dosage. Lastly, PATC-PDMDAAC has more advantage than conventional flocculants in the treatment of low-temperature and low-turbidity water in the Xiangjiang River.