Directed Orthogonal Self-Assembly of Homochiral Coordination Polymers for Heterogeneous Enantioselective Hydrogenation

Three in one: Orthogonal coordination of FeII and RhI with a single heteroditopic ligand results in the formation of self‐supported heterogeneous chiral catalysts (see scheme). The compounds are highly active, enantioselective, and reusable in the heterogeneous asymmetric hydrogenation of various fu...

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Published inAngewandte Chemie (International ed.) Vol. 49; no. 21; pp. 3627 - 3630
Main Authors Yu, Liting, Wang, Zheng, Wu, Jiang, Tu, Shujiang, Ding, Kuiling
Format Journal Article
LanguageEnglish
Published Weinheim Wiley-VCH Verlag 10.05.2010
WILEY-VCH Verlag
WILEY‐VCH Verlag
Wiley
Subjects
asymmetric catalysis
Catalysis
Chemistry
Chemistry, Multidisciplinary
heterogeneous catalysis
Hydrogenation
Microscopy, Electron, Scanning
Molecular Structure
Physical Sciences
Polymers - chemistry
rhodium
Rhodium - chemistry
Science & Technology
Stereoisomerism
supramolecular chemistry
heterogeneous catalysis
COMPLEXES
METAL-ORGANIC FRAMEWORK
MULTIFUNCTIONALIZATION
PRINCIPLE
asymmetric catalysis
SUPPORTED CHIRAL CATALYSTS
AMINE
hydrogenation
CARBONYL-ENE
LIGANDS
ASYMMETRIC HYDROGENATION
supramolecular chemistry
rhodium
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Summary:Three in one: Orthogonal coordination of FeII and RhI with a single heteroditopic ligand results in the formation of self‐supported heterogeneous chiral catalysts (see scheme). The compounds are highly active, enantioselective, and reusable in the heterogeneous asymmetric hydrogenation of various functionalized olefin derivatives.
Bibliography:http://dx.doi.org/10.1002/anie.200906405
Chinese Academy of Sciences
Science and Technology Commission of Shanghai Municipality
Merck Research Laboratories
ark:/67375/WNG-LRMLZTKB-T
National Natural Science Foundation of China - No. 20632060; No. 20821002
istex:930E91B2BA85BA9683478C6D38E83B70B9E65EAC
ArticleID:ANIE200906405
Financial support from the National Natural Science Foundation of China (Nos. 20632060, 20821002), the Chinese Academy of Sciences, the Major Basic Research Development Program of China (Grant Nos. 2010CB833300, 2006CB806106), the Science and Technology Commission of Shanghai Municipality, and Merck Research Laboratories is gratefully acknowledged.
Major Basic Research Development Program of China - No. 2010CB833300; No. 2006CB806106
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200906405