Directed Orthogonal Self-Assembly of Homochiral Coordination Polymers for Heterogeneous Enantioselective Hydrogenation
Three in one: Orthogonal coordination of FeII and RhI with a single heteroditopic ligand results in the formation of self‐supported heterogeneous chiral catalysts (see scheme). The compounds are highly active, enantioselective, and reusable in the heterogeneous asymmetric hydrogenation of various fu...
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Published in | Angewandte Chemie (International ed.) Vol. 49; no. 21; pp. 3627 - 3630 |
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Main Authors | , , , , |
Format | Journal Article |
Language | English |
Published |
Weinheim
Wiley-VCH Verlag
10.05.2010
WILEY-VCH Verlag WILEY‐VCH Verlag Wiley |
Subjects | |
Online Access | Get full text |
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Summary: | Three in one: Orthogonal coordination of FeII and RhI with a single heteroditopic ligand results in the formation of self‐supported heterogeneous chiral catalysts (see scheme). The compounds are highly active, enantioselective, and reusable in the heterogeneous asymmetric hydrogenation of various functionalized olefin derivatives. |
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Bibliography: | http://dx.doi.org/10.1002/anie.200906405 Chinese Academy of Sciences Science and Technology Commission of Shanghai Municipality Merck Research Laboratories ark:/67375/WNG-LRMLZTKB-T National Natural Science Foundation of China - No. 20632060; No. 20821002 istex:930E91B2BA85BA9683478C6D38E83B70B9E65EAC ArticleID:ANIE200906405 Financial support from the National Natural Science Foundation of China (Nos. 20632060, 20821002), the Chinese Academy of Sciences, the Major Basic Research Development Program of China (Grant Nos. 2010CB833300, 2006CB806106), the Science and Technology Commission of Shanghai Municipality, and Merck Research Laboratories is gratefully acknowledged. Major Basic Research Development Program of China - No. 2010CB833300; No. 2006CB806106 ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
ISSN: | 1433-7851 1521-3773 |
DOI: | 10.1002/anie.200906405 |