Microwave Chemistry in Silicon Carbide Reaction Vials: Separating Thermal from Nonthermal Effects

Running oil‐bath chemistry in a microwave! Using reaction vials made out of strongly microwave‐absorbing silicon carbide (SiC) in a microwave reactor simulates experiments conducted in an autoclave with conductive heating because of the efficient shielding of the electromagnetic field by the SiC via...

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Bibliographic Details
Published inAngewandte Chemie (International ed.) Vol. 48; no. 44; pp. 8321 - 8324
Main Authors Obermayer, David, Gutmann, Bernhard, Kappe, C. Oliver
Format Journal Article
LanguageEnglish
Published Weinheim Wiley-VCH Verlag 19.10.2009
WILEY-VCH Verlag
WILEY‐VCH Verlag
Subjects
Carbon Compounds, Inorganic - chemistry
electromagnetic fields
Ionic Liquids
Magnetics
microwave chemistry
Microwaves
silicon carbide
Silicon Compounds - chemistry
Temperature
thermochemistry
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Summary:Running oil‐bath chemistry in a microwave! Using reaction vials made out of strongly microwave‐absorbing silicon carbide (SiC) in a microwave reactor simulates experiments conducted in an autoclave with conductive heating because of the efficient shielding of the electromagnetic field by the SiC vial. This technology makes it possible to study the significance of microwave effects.
Bibliography:http://dx.doi.org/10.1002/anie.200904185
ArticleID:ANIE200904185
This work was supported by a grant from the Christian Doppler Society (CDG). We acknowledge Anton Paar GmbH for the provision of the Monowave microwave reactor and technical support and thank Dr. Jennifer M. Kremsner for early contributions to this work.
Christian Doppler Society (CDG)
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ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200904185