Boron- and Fluorine-Containing Mesoporous Carbon Nitride Polymers: Metal-Free Catalysts for Cyclohexane Oxidation

Beefed up with B,F: A boron‐ and fluorine‐enriched carbon nitride polymeric semiconductor was synthesized by a facile one‐step process using 1‐butyl‐3‐methylimidazolium tetrafluoroborate as a soft template. The resulting materials show an advantageous “morel‐like” mesopore structure (see picture) wi...

Full description

Saved in:
Bibliographic Details
Published inAngewandte Chemie (International ed.) Vol. 49; no. 19; pp. 3356 - 3359
Main Authors Wang, Yong, Zhang, Jinshui, Wang, Xinchen, Antonietti, Markus, Li, Haoran
Format Journal Article
LanguageEnglish
Published Weinheim Wiley-VCH Verlag 26.04.2010
WILEY-VCH Verlag
WILEY‐VCH Verlag
Subjects
carbon nitride
ionic liquids
mesoporous materials
oxidation
polymers
Online AccessGet full text

Cover

More Information
Summary:Beefed up with B,F: A boron‐ and fluorine‐enriched carbon nitride polymeric semiconductor was synthesized by a facile one‐step process using 1‐butyl‐3‐methylimidazolium tetrafluoroborate as a soft template. The resulting materials show an advantageous “morel‐like” mesopore structure (see picture) with narrow pore size distribution and good photoactivity under visible light. The materials are also good catalysts for the selective oxidation of cyclohexane.
Bibliography:http://dx.doi.org/10.1002/anie.201000120
This work was supported by the ENERCHEM project of the MPI, by the National Natural Science Foundation of China (No. 20806065), and by the China Postdoctoral Special Science Foundation funded project (No. 200902630).
MPI
National Natural Science Foundation of China - No. 20806065
China Postdoctoral Special Science Foundation - No. 200902630
ark:/67375/WNG-D1W34C6J-Z
ArticleID:ANIE201000120
istex:135771BD8ADBFDAEB14A9C23B906273F23C4E219
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201000120