Transformation of Nitrile to Cyanide and Aldehyde Using a Cobalt(II) Complex and Dioxygen

Canning a carbon: During oxidation with O2, the cobalt(II) complex [Co(salmdpt)] (salmdptH2=bis[3‐(salicylideneimino)‐propyl]methylamine) reacts with a nitrile substrate to form the cyanide complex [Co(salmdpt)CN] (see structure) and the corresponding aldehyde, which contains one less carbon atom th...

Full description

Saved in:
Bibliographic Details
Published inAngewandte Chemie (International ed.) Vol. 46; no. 41; pp. 7775 - 7777
Main Authors Müller, Jörg, Würtele, Christian, Walter, Olaf, Schindler, Siegfried
Format Journal Article
LanguageEnglish
Published Weinheim Wiley-VCH Verlag 01.01.2007
WILEY-VCH Verlag
WILEY‐VCH Verlag
Wiley
Subjects
Chemistry
Chemistry, Multidisciplinary
cobalt
coordination chemistry
cyanides
oxygen
peroxo ligands
Physical Sciences
Science & Technology
CRYSTAL-STRUCTURE
COPPER(II)
cyanides
HYDROXYLATION
REACTIVITY
cobalt
peroxo ligands
CLEAVAGE
ADDUCT
LIGANDS
coordination chemistry
C-C BOND
ACETONITRILE
oxygen
CRYPTATE
Online AccessGet full text

Cover

More Information
Summary:Canning a carbon: During oxidation with O2, the cobalt(II) complex [Co(salmdpt)] (salmdptH2=bis[3‐(salicylideneimino)‐propyl]methylamine) reacts with a nitrile substrate to form the cyanide complex [Co(salmdpt)CN] (see structure) and the corresponding aldehyde, which contains one less carbon atom than the starting nitrile.
Bibliography:http://dx.doi.org/10.1002/anie.200701408
istex:B3E2CDA7E9D20961A789CF606CAA1E1B05EBDEFB
ark:/67375/WNG-L4HWF2Z7-C
ArticleID:ANIE200701408
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200701408