Synthesis of Functional Polymers by Post-Polymerization Modification

• Published in: Angewandte Chemie (International ed.) Vol. 48; no. 1; pp. 48 - 58
• Main Authors: Gauthier, Marc A, Gibson, Matthew I, Klok, Harm-Anton
• Format: Journal Article
• Language: English
• Published: Weinheim Wiley-VCH Verlag 01.01.2009; WILEY-VCH Verlag; WILEY‐VCH Verlag
• Subjects: copolymerization; functional monomers; polymer-analogous reactions; polymerization; polymers
• ISSN: 1433-7851; 1521-3773
• DOI: 10.1002/anie.200801951

Post-polymerization modification is based on the direct polymerization or copolymerization of monomers bearing chemoselective handles that are inert towards the polymerization conditions but can be quantitatively converted in a subsequent step into a broad range of other functional groups. The success of this method is based on the excellent conversions achievable under mild conditions, the excellent functional-group tolerance, and the orthogonality of the post-polymerization modification reactions. This Review surveys different classes of reactive polymer precursors bearing chemoselective handles and discusses issues related to the preparation of these reactive polymers by direct polymerization of appropriately functionalized monomers as well as the post-polymerization modification of these precursors into functional polymers.