Experimental Study on the Mechanical Properties and Microstructure of Metakaolin-Based Geopolymer Modified Clay

• Published in: Molecules (Basel, Switzerland) Vol. 27; no. 15; p. 4805
• Main Authors: Shi, Xianzeng, Zha, Qingkun, Li, Shuqing, Cai, Guojun, Wu, Dun, Zhai, Chaojiao
• Format: Journal Article
• Language: English
• Published: Basel MDPI AG 27.07.2022; MDPI
• Subjects: Basicity; Caustic soda; Cement; Cementing; Clay; Compressive strength; geopolymer; Geopolymers; Humidity; Mechanical properties; Metakaolin; Mineral reserves; Polymerization; Polymers; Scanning electron microscopy; scanning electron microscopy (SEM); Silica; Sodium; Sodium hydroxide; sodium hydroxide (NaOH); Soil improvement; Soil mixtures; Soils; unconfined compressive strength; X-ray diffraction; China
• ISSN: 1420-3049; 1420-3049
• DOI: 10.3390/molecules27154805

Clay is found in some countries all over the world. It usually has low compressive strength and cannot be used as a bearing material for subgrade soil. In this paper, the influence of basicity on a metakaolin-based polymer binder to improve clay was studied. The effects of the molar concentration of the alkali activator, different concentration of the metakaolin-based geopolymer and curing time on unconfined compressive strength were studied. The alkali activator-to-ash ratio was maintained at 0.7. The percentage of metakaolin added to the soil relative to metakaolin and soil mixture was 6%, 8%, 10% and 12%. The sodium hydroxide concentrations are 2M, 4M, 6M and 8M. Unconfined compressive strength (UCS) was tested on days 3, 7, 14 and 28, respectively. Compared with original clay, the results show that the unconfined compressive strength increases with the increase in metakaolin content and molar concentration of NaOH. The maximum compressive strength of the sample with NaOH concentration of 8M and percentage of 12% was 4109 kN on the 28th day, which is about 112% higher than that of the original clay. Scanning electron microscopy (SEM) and X-ray diffraction (XRD) results showed that the cementing compound covered the clay particles due to the reaction of the geopolymer with the clay, resulting in the formation of adhesive particles. The main purpose of this study is to verify the effectiveness and stability of metakaolin-based geopolymer binder polymerization under normal temperature and a strong alkali environment. The results can provide parameters for the application and promotion of metakaolin-based geopolymers in soil improvement engineering.