Formulation of Visible Light-Curable Glass-Ionomer Cements Containing N-Vinylpyrrolidone

• Published in: Journal of macromolecular science. Part A, Pure and applied chemistry Vol. 35; no. 10; pp. 1631 - 1650
• Main Authors: Xie, Dong, Culbertson, Bill M., Johnston, William M.
• Format: Journal Article
• Language: English
• Published: Colchester Taylor & Francis Group 01.10.1998; Taylor & Francis
• Subjects: Applied sciences; Bending strength; Biological and medical sciences; Compressive Strength; Elastic moduli; Exact sciences and technology; Free radical polymerization; Free radical reactions; Graft Ratio; Grafting (chemical); Head and neck surgery. Maxillofacial surgery. Dental surgery. Orthodontics; Light-Curable N-vinylpyrrolidone Modified Glass-Ionomer Cements; Mathematical models; Maxillofacial surgery. Dental surgery. Orthodontics; Mechanical properties; Medical sciences; Optimal Formulation; Physicochemistry of polymers; Polymerization; Polymers and radiations; Statistical Design of Experiment; Stress-Strain Curve; Surgery (general aspects). Transplantations, organ and tissue grafts. Graft diseases; Tensile strength; Terpolymers; Ionomer; Terpolymer; Organic isocyanate; Acrylic acid copolymer; Glass; Mechanical properties; Acrylamide derivative copolymer; Dispersion reinforced material; Hydroxyethyl methacrylate copolymer; Dental restauration; Experimental study; Property processing relationship; Itaconic derivative copolymer; Composite material; Property formulation relationship; Crosslinked copolymer; Chemical modification; Experimental design; Statistical model; Dental cement; Pyrrolidone(vinyl) copolymer; Light sensitive copolymer; Biomaterial; Photochemical copolymerization
• ISSN: 1060-1325; 1520-5738
• DOI: 10.1080/10601329808000976

The best graft ratio of the light-curable N-vinylpyrrolidone (NVP) modified terpolymers (LC NVPM TPs) with the molar ratio of 8:2:1 (acrylic acid:itaconic acid:NVP) and the optimal formulation for this light-curable glass-ionomer cement, based on the best graft ratio, were determined. Statistical models were utilized to predict the optimal formulations. The terpolymer was prepared using a free-radical polymerization reaction. The LC NVPM TPs were produced by grafting 2-isocyanatoethyl methacrylate (IEM) onto the terpolymer. Cements were formed by both light-curing and the reaction with glass particles. Compressive strength was used as the basic screening property to find the optimal formulation. Diametral tensile and flexural strengths were also used to evaluate the mechanical properties. The strength values were recorded on the specimens conditioned in distilled water at 37&C for 24 hours or 7 days. The best graft ratio for IEM in this system was 15% of the terpolymer by a molar ratio. The optimal formulation was found to be at the weight ratio of 55:15:30 [LC NVPM TP:2-hydroxyethyl methacrylate (HEMA): H 2 O]. Stress-strain curves showed that a relatively high amount of water in the formulation led to higher elastic modulus and proportional limit and lower malleability, whereas a relatively high amount of HEMA gave the opposite results. The light-curable NVP modified glass-ionomer cements showed statistically significantly higher values in compressive, diametral tensile, and flexural strengths than the commercial Vitremer TM .