Graphitic carbon nitride based nanocomposites for the photocatalysis of organic contaminants under visible irradiation: Progress, limitations and future directions

• Published in: The Science of the total environment Vol. 633; pp. 546 - 559
• Main Authors: Xu, Bentuo, Ahmed, Mohammad Boshir, Zhou, John L., Altaee, Ali, Xu, Gang, Wu, Minghong
• Format: Journal Article
• Language: English
• Published: Netherlands Elsevier B.V 15.08.2018
• Subjects: absorption; carbon nitride; Co-doping; dissolved organic matter; dissolved oxygen; energy efficiency; environmental factors; g-C3N4 photocatalyst; graphene; Immobilization; irradiation; methyl orange; Morphology; nanocomposites; Photocatalysis; photocatalysts; photolysis; potassium; solar radiation; surface area; temperature; titanium dioxide; wastewater; wastewater treatment; water pollution; Immobilization; Photocatalysis; Morphology; g-C3N4 photocatalyst; Co-doping; g-CN photocatalyst
• ISSN: 0048-9697; 1879-1026; 1879-1026
• DOI: 10.1016/j.scitotenv.2018.03.206

Graphitic carbon nitride (g-C3N4) has drawn great attention recently because of its visible light response, suitable energy band gap, good redox ability, and metal-free nature. g-C3N4 can absorb visible light directly, therefore has better photocatalytic ability under solar irradiation and is more energy-efficient than TiO2. However, pure g-C3N4 still has the drawbacks of insufficient light absorption, small surface area and fast recombination of photogenerated electron and hole pairs. This review summarizes the recent progress in the development of g-C3N4 nanocomposites to photodegrade organic contaminants in water. Element doping especially by potassium has been reported to be an efficient method to promote the degradation efficacy. In addition, compound doping improves photodegradation performance of g-C3N4, especially Ag3PO4-g-C3N4 which can completely degrade 10mgL−1 of methyl orange under visible light irradiation in 5min, with the rate constant (k) as high as 0.236min−1. Moreover, co-doping enhances the photodegradation rate of multiple contaminants while immobilization significantly improves catalyst stability. Most of g-C3N4 composites possess high reusability enabling their practical applications in wastewater treatment. Furthermore, environmental conditions such as solution pH, reaction temperature, dissolved oxygen, and dissolved organic matter all have important effects on the photocatalytic ability of g-C3N4 photocatalyst. Future work should focus on the synthesis of innovative g-C3N4 nanocomposites for the efficient removal of organic contaminants in water and wastewater. [Display omitted] •g-C3N4 catalyst performs better than TiO2 in visible photocatalysis of dyes.•Photodegradation by g-C3N4 is particularly enhanced by K-doping.•Compound doping especially Ag3PO4-g-C3N4 improves photodegradation effect.•Co-doping can degrade multiple contaminants with high degradation rate constant.•Synthesized g-C3N4 nanocomposites have shown good reusability.