Dispersion and characterization of thermoplastic polyurethane/multiwalled carbon nanotubes by melt mixing

• Published in: Journal of applied polymer science Vol. 122; no. 6; pp. 3744 - 3750
• Main Authors: Benedito, Adolfo, Buezas, Ignacio, Giménez, Enrique, Galindo, Begoña, Ortega, Amaya
• Format: Journal Article Conference Proceeding
• Language: English
• Published: Hoboken Wiley Subscription Services, Inc., A Wiley Company 15.12.2011; Wiley; Wiley Subscription Services, Inc
• Subjects: Applied sciences; Composites; Design engineering; Dispersions; Dynamic tests; Dynamics; Exact sciences and technology; extrusion; Forms of application and semi-finished materials; Materials science; Polymer industry, paints, wood; Polymers; Polyurethane resins; polyurethanes; Screws; Technology of polymers; Thermoplastic resins; Urethane thermoplastic elastomers; Viscoelasticity; Electrical conductivity; Electrical properties; Dispersion degree; Double screw extruder; Carbon nanotubes; Thermoplastic rubber; Experimental study; polyurethanes; Thermal stability; Polyurethane elastomer; Thermal properties; Multiwalled nanotube; Dynamic mechanical properties; Experimental design; dispersions; Morphology; Concentration effect; Extrusion; Rheological properties
• ISSN: 0021-8995; 1097-4628; 1097-4628
• DOI: 10.1002/app.34788

The dispersion of multiwalled carbon nanotubes (MWCNT) in thermoplastic polyurethanes (TPUs) was evaluated in a corotative twin‐screw extruder through a melt‐blending process. A specific experimental design was prepared with different parameters, such as screw speed, screw design, and carbon nanotube loading, taken into account. The obtained samples were characterized by thermogravimetric analysis, light transmission microscopy, field emission scanning electron microscopy, dynamic rheometry, dynamic mechanical analysis, and electrical conductivity. This work focuses on the influence of the compounding parameters in the dispersion quality of MWCNTs in a TPU matrix to optimize them for an industrial scaleup. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011