Functional manganese ferrite/graphene oxide nanocomposites: effects of graphene oxide on the adsorption mechanisms of organic MB dye and inorganic As(v) ions from aqueous solution

• Published in: RSC advances Vol. 8; no. 22; pp. 12376 - 12389
• Main Authors: Lan Huong, Pham Thi, Tu, Nguyen, Lan, Hoang, Thang, Le Hong, Van Quy, Nguyen, Tuan, Pham Anh, Dinh, Ngo Xuan, Phan, Vu Ngoc, Le, Anh-Tuan
• Format: Journal Article
• Language: English
• Published: England Royal Society of Chemistry 01.01.2018; The Royal Society of Chemistry
• Subjects: Adsorbates; Adsorption; Aqueous solutions; Arsenic; Binding sites; Chemical precipitation; Chemistry; Computer simulation; Conjugation; Dyes; Ferrites; Functional groups; Graphene; Heavy metals; Ionic interactions; Isotherms; Magnetic properties; Manganese ions; Methylene blue; Nanocomposites; Pollutants
• ISSN: 2046-2069; 2046-2069
• DOI: 10.1039/c8ra00270c

In this study, manganese ferrite-graphene oxide (MFO-GO) nanocomposites were prepared via a co-precipitation reaction of Fe 3+ and Mn 2+ ions in a GO suspension. The effects of graphene oxide on the physicochemical characteristics, magnetic properties and adsorption activities of the MFO-GO nanocomposites were studied. Methylene blue (MB) and arsenic( v ) were used in this study as model water pollutants. With an increase in the GO content in the range of 10 wt% to 50 wt%, the removal efficiency for both MB dye and arsenic( v ) ions was improved. Our adsorption data revealed that the adsorption behavior of MB dye showed good agreement with the Langmuir isotherm model and pseudo-second-order equation, whereas the Freundlich isotherm model was more suitable for simulating the adsorption process of arsenic( v ) ions on the MFO-GO nanocomposites. In addition, an important role of the GO content in the adsorption mechanisms of both MB dye and arsenic( v ) ions was found, in which GO nanosheets play a key role in the mechanisms of electrostatic/ionic interactions, oxygen-containing groups and π-π conjugation in the case of the adsorption of MB dye, whereas the role of the GO content is mainly related to the mechanism of electrostatic/ionic interactions in the case of the adsorption of arsenic( v ). Graphene oxide has the functions of increasing the number of active binding sites comprising oxygen-containing functional groups, reducing the agglomeration of MFO nanoparticles, increasing the number of adsorption sites, and improving the electrostatic/ionic interactions between adsorbents and adsorbates in order to enhance the adsorption performance of cationic organic dyes and/or heavy metal anions from aqueous solutions. In this study, manganese ferrite-graphene oxide (MFO-GO) nanocomposites were prepared via a co-precipitation reaction of Fe 3+ and Mn 2+ ions in a GO suspension.