The influence of wrinkled ZnO on inverted low bandgap thin film solar cells

• Published in: Solar energy materials and solar cells Vol. 101; pp. 180 - 185
• Main Authors: Chen, Chao-Shuo, Yang, Po-Ching, Shen, Yu-Min, Ma, Shou-Yuan, Shiu, Shu-Chia, Hung, Shih-Che, Lin, Shang-Hong, Lin, Ching-Fuh
• Format: Journal Article
• Language: English
• Published: Amsterdam Elsevier B.V 01.06.2012; Elsevier
• Subjects: Applied sciences; Banded structure; Direct energy conversion and energy accumulation; Electrical engineering. Electrical power engineering; Electrical power engineering; Energy; Exact sciences and technology; Inverted structure; Leakage current; Nanorods; Natural energy; Penetration; Photoelectric conversion; Photovoltaic cells; Photovoltaic conversion; Polymer solar cells; Polymers; Solar cells; Solar cells. Photoelectrochemical cells; Solar energy; Thin films; Wrinkle; Zinc oxide; ZnO; ZnO; Leakage current; Wrinkle; Inverted structure; Polymer solar cells; High performance; Active layer; Polymer; Organic solar cells; Thin film; Solar cell; Thin film cell; Morphology; Zinc oxide; Titanium oxide; Nanorod; Growth from solution
• ISSN: 0927-0248; 1879-3398
• DOI: 10.1016/j.solmat.2012.01.042

We discovered that fringe structures of ZnO film in solar cells of inverted structures penetrate through the active layer made of low bandgap polymers. The ZnO penetration leads to leakage current of the solar cells. To prevent the ZnO penetration, the thin film morphology was modified. By changing the solvent and inserting TiO2 nanorods between ZnO film and the active layer, penetration can be avoided, so Rsh is improved from 110.3Ωcm2 to 374.7Ωcm2 and Voc from 0.36V to 0.66V. This result provides a promising route for employing low bandgap polymers to air-stable inverted structures with solution process. It is possible that inverted low bandgap polymer solar cells can achieve the goals of high performance and air stability. ► The wrinkled ZnO would penetrate through PCDTBT:PCBM blend. ► The ZnO penetration leads to large leakage current. ► Two methods have been demonstrated to prevent ZnO penetration. ► Thin film low band gap polymer is matched to an inverted structure.