Ennoblement, corrosion, and biofouling in brackish seawater: Comparison between six stainless steel grades

• Published in: Bioelectrochemistry (Amsterdam, Netherlands) Vol. 120; pp. 27 - 42
• Main Authors: Huttunen-Saarivirta, E., Rajala, P., Marja-aho, M., Maukonen, J., Sohlberg, E., Carpén, L.
• Format: Journal Article
• Language: English
• Published: Netherlands Elsevier B.V 01.04.2018; Elsevier BV
• Subjects: Actinobacteria - isolation & purification; Biofilms; Biofouling; Brackish sea water; Chemical analysis; Cooling water; Corrosion; Dielectric Spectroscopy; Electrochemical impedance spectroscopy; Electrochemical measurements; Electrochemistry; Ennoblement; Microbially induced corrosion (MIC); Next-generation sequencing; Open circuit voltage; Polymerase chain reaction; Proteobacteria - isolation & purification; Scanning electron microscopy; Seawater; Seawater - chemistry; Seawater - microbiology; Spectroscopy; Stainless steel; Stainless Steel - chemistry; Stainless steels; Water analysis; Electrochemical measurements; Ennoblement; Biofouling; Stainless steel; Brackish sea water; Microbially induced corrosion (MIC)
• ISSN: 1567-5394; 1878-562X
• DOI: 10.1016/j.bioelechem.2017.11.002

In this work, six common stainless steel grades were compared with respect to ennoblement characteristics, corrosion performance and tendency to biofouling in brackish sea water in a pilot-scale cooling water circuit. Two tests were performed, each employing three test materials, until differences between the materials were detected. Open circuit potential (OCP) was measured continuously in situ. Potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) measurements were conducted before and after the tests. Exposed specimens were further subjected to examinations by scanning electron microscopy (SEM) and energy-dispersive spectroscopy (EDS), and the biofouling was studied using epifluorescence microscopy, quantitative polymerase chain reaction (qPCR) and high-throughput sequencing (HTP sequencing). The results revealed dissimilarities between the stainless steel grades in corrosion behaviour and biofouling tendency. The test material that differed from the most of the other studied alloys was grade EN 1.4162. It experienced fastest and most efficient ennoblement of OCP, its passive area shrank to the greatest extent and the cathodic reaction was accelerated to a significant degree by the development of biofilm. Furthermore, microbiological analyses revealed that bacterial community on EN 1.4162 was dominated by Actinobacteria, whereas on the other five test materials Proteobacteria was the main bacterial phylum. •Ennoblement, corrosion and biofouling of six stainless steels were compared.•Tests were carried out in a pilot-scale cooling water circuit using brackish water.•Grade EN 1.4162 showed a faster ennoblement than the other studied grades.•Biofilm formation increased pitting corrosion tendency of majority of test alloys.•Actinobacteria dominated the biofilm on EN 1.4162, Proteobacteria on other grades.