Improvement of the water selectivity of ULTEM poly(ether imide) pervaporation films by an allylamine-plasma-polymerized layer

• Published in: Journal of applied polymer science Vol. 97; no. 5; pp. 2088 - 2096
• Main Authors: Kaba, M., Raklaoui, N., Guimon, M.-F., Mas, A.
• Format: Journal Article
• Language: English
• Published: Hoboken Wiley Subscription Services, Inc., A Wiley Company 05.09.2005; Wiley
• Subjects: Applied sciences; Chemical Sciences; Exact sciences and technology; Exchange resins and membranes; Forms of application and semi-finished materials; membranes; plasma polymerization; polyimides; Polymer industry, paints, wood; Polymers; surfaces; Technology of polymers; Water; Transport properties; Ethanol; polyimides; Aromatic polymer; Allylic amine polymer; Experimental study; Property processing relationship; Quantitative surface analysis; Glow discharge polymerization; Surface treatment; Polyelectrolyte; Structure processing relationship; membranes; Wettability; plasma polymerization; surfaces; Morphology; Selective permeability; Surface properties; Membrane; Etherimide polymer; Plasma deposition; Pervaporation; polymerization; plasma
• ISSN: 0021-8995; 1097-4628
• DOI: 10.1002/app.21684

The wettability and surface energy of extruded ULTEM poly(ether imide) films strongly increased (the water contact angle varied from 75 to 38° and the surface energy varied from 45.3 to 59.5 mJ m−2, respectively) with the deposition of an allylamine‐plasma‐polymerized layer and were characterized with X‐ray photoelectron spectroscopy, scanning electron microscopy, and atomic force microscopy according to the experimental parameters. Pervaporation tests for dehydrating the water/ethanol azeotropic mixture were performed at 40°C with nontreated and plasma‐treated ULTEM films for 15, 30, 60, and 120 min. No significant difference was noticed in the total flow (ca. 2.5 g/m2 h) among the various films. However, for the 30‐min duration, a great increase in the water selectivity from 850 to 10,850 was measured, and it was related to the higher N/C ratio and the presence of amide groups on the surface. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 97: 2088–2096, 2005