Influence of different heat treatments on the surface properties and catalytic performance of carbon nanotube in ozonation

• Published in: Applied catalysis. B, Environmental Vol. 101; no. 1-2; pp. 74 - 80
• Main Authors: Liu, Zheng-Qian, Ma, Jun, Cui, Yu-Hong, Zhao, Lei, Zhang, Bei-Ping
• Format: Journal Article
• Language: English
• Published: Kidlington Elsevier B.V 22.11.2010; Elsevier
• Subjects: Carbon nanotube; Carbon nanotubes; Catalysis; Catalysts; Catalytic ozonation; Chemistry; Exact sciences and technology; General and physical chemistry; Heat treatment; Oxalic acid; Surface physical chemistry; Surface properties; Temperature; Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry; Carbon nanotube; Heat treatment; Oxalic acid; Catalytic ozonation; Catalytic reaction; Surface reaction; Carbon nanotubes; Carbon; Surface treatment; Degradation; Chemical reduction; Heterogeneous catalysis; Atmosphere; Surface properties; pH; Dicarboxylic acid; Aqueous solution; Rate constant; Release; Environmental protection
• ISSN: 0926-3373; 1873-3883
• DOI: 10.1016/j.apcatb.2010.09.009

[Display omitted] ▶ Heat treatment has a significant influence on the activity of CNT in ozonation. ▶ Heat treatment increases the basic property of CNT. ▶ CNT with a higher pHPZC has a higher activity in ozonation. ▶ A linear relationship is observed between pHPZC and rate constant in ozonation. The influences of treatment conditions, gas atmosphere (N2 and H2) and temperature (450°C and 950°C), on the surface properties and catalytic performance of carbon nanotube (CNT) were investigated for the degradation of oxalic acid in aqueous solution by the process of catalytic ozonation. No obvious change on the textural properties of CNT is found after heat treatment, while the results of Boehm titration clearly indicate the reduction of acidic groups and the increase of basic groups on CNT surface after heat treatment under different conditions, and then a significant improvement on oxalic acid removal by CNT catalytic ozonation is obtained. The heat treatment of CNT under H2 atmosphere is more effective in eliminating acidic groups and increasing basic groups than the case of N2 atmosphere at the same temperature, which results in higher catalytic activity and lower total organic carbon (TOC) release in ozonation correspondingly. A linear relationship is observed between the pH at the point of zero charge (pHPZC) of CNT and the rate constant for ozonation of oxalic acid in the presence of CNT with different treatments. It is suggested that heat treatment can increase the basic property of CNT, which can enhance the contribution of surface reactions to the whole reactions for ozonation of oxalic acid.