Influence of N-vynilcarbazole on the photopolymerization process and properties of epoxy-acrylate interpenetrating polymer networks

• Published in: e-Polymers Vol. 16; no. 6; pp. 429 - 435
• Main Authors: Samoilenko, Tetiana F., Iarova, Natalia V., Ostapiuk, Svitlana M., Tkalich, Maksym H., Vorontsova, Liubov O., Klymchuk, Dmytro O., Brovko, Oleksandr O.
• Format: Journal Article
• Language: English
• Published: Berlin De Gruyter 01.11.2016; Walter de Gruyter GmbH
• Subjects: Conversion; Electronics; epoxy-acrylate interpenetrating polymer networks; Fourier transforms; Infrared spectroscopy; Interpenetrating networks; Materials science; N-vinylcarbazole; Photopolymerization; photosensitizer; Polymers; Sunlight; sunlight-induced photopolymerization; UV-curing
• ISSN: 2197-4586; 1618-7229
• DOI: 10.1515/epoly-2016-0123

Photocured simultaneous epoxy-acrylate interpenetrating polymer networks (IPNs) were formed both under irradiation by UV-lamp and natural sunlight. The conversion degrees of functional groups were calculated by using data obtained from Fourier transform infrared (FTIR) spectroscopy. The influence of N-vynilcarbazole (NVC) as a photosensitizer on the kinetics of IPN photopolymerization was investigated. The conversion degrees of epoxy groups were revealed to increase significantly with the addition of NVC to the given systems. The phase morphology of IPNs was analyzed by optical and scanning electronic microscopy as well as by dynamic mechanical analysis (DMA). The data obtained using DMA method, which was used for analyzing the IPN samples with different component ratios, indicate the formation of both phase-separated and single-phase IPNs. The phase separation is occurred only in NVC-containing 50:50 IPN.