Direct Azidation of Phenols

Direct azidation of phenols was developed. By treating chloroimidazolinium chloride 1b and sodium azide with phenol in the presence of a secondary amine in methoxyethanol, ortho‐azidation of phenol was achieved. Direct azidation of phenols was achieved by reaction of chloroimidazolinium cloride 1b,...

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Published inEuropean journal of organic chemistry Vol. 2019; no. 33; pp. 5824 - 5827
Main Authors Kitamura, Mitsuru, Murakami, Kento, Koga, Tatsuya, Eto, Takashi, Ishikawa, Akihiro, Shimooka, Hirokazu, Okauchi, Tatsuo
Format Journal Article
LanguageEnglish
Published WEINHEIM Wiley 08.09.2019
Wiley Subscription Services, Inc
Subjects
Azidation
Azides
Chemistry
Chemistry, Organic
Phenols
Physical Sciences
Science & Technology
Sodium azides
HALIDES
CLICK CHEMISTRY
DIAZOTRANSFER
SAFE
TRANSFER REAGENT
Azidation
Azides
NUCLEOSIDE
AMINES
EFFICIENT DIAZO-TRANSFER
Phenols
ARYL AZIDES
DERIVATIVES
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Summary:Direct azidation of phenols was developed. By treating chloroimidazolinium chloride 1b and sodium azide with phenol in the presence of a secondary amine in methoxyethanol, ortho‐azidation of phenol was achieved. Direct azidation of phenols was achieved by reaction of chloroimidazolinium cloride 1b, secondary amine, and sodium azide in methoxyethanol.
ISSN:1434-193X
1099-0690
DOI:10.1002/ejoc.201900967