Mechanical Properties of Highly Porous Super Liquid-Repellent Surfaces

• Published in: Advanced functional materials Vol. 26; no. 27; pp. 4914 - 4922
• Main Authors: Paven, Maxime, Fuchs, Regina, Yakabe, Taro, Vollmer, Doris, Kappl, Michael, Itakura, Akiko N., Butt, Hans-Jürgen
• Format: Journal Article
• Language: English
• Published: Blackwell Publishing Ltd 19.07.2016
• Subjects: characterization tools; colloidal probe; Colloids; Force measurement; functional coatings; Mechanical testing; Micrometers; Nanostructure; porous materials; Strength; superhydrophobic/hydrophilic surfaces; Tuning; Wettability
• ISSN: 1616-301X; 1616-3028
• DOI: 10.1002/adfm.201600627

Surfaces with self‐cleaning properties are desirable for many applications. Conceptually, super liquid‐repellent surfaces are required to be highly porous on the nano‐ or micrometer scale, which inherently makes them mechanically weak. Optimizing the balance of mechanical strength and liquid repellency is a core aspect toward applications. However, quantitative mechanical testing of porous, super liquid‐repellent surfaces is challenging due to their high surface roughness at different length scales and low stress tolerance. For this reason, mechanical testing is often performed qualitatively. Here, the mechanical responses of soot‐templated super liquid‐repellent surfaces are studied qualitatively by pencil and finger scratching and quantitatively by atomic force microscopy, colloidal probe force measurements, and nanoindentation. In particular, colloidal probe force measurements cover the relevant force and length scales. The effective elastic modulus, the plastic work Wplastic and the effective adhesive work Wadhesive are quantified. By combining quantitative information from force measurements with measurements of surface wetting properties, it is shown that mechanical strength can be balanced against low wettability by tuning the reaction parameters. Super liquid‐repellent surfaces have self‐cleaning properties and are desirable for many applications. These surfaces are highly porous on the nano‐ or micrometer scale, what inherently makes them mechanically weak. It is demonstrated that force‐sensitive measurements using the colloidal probe technique can be used to optimize for mechanical strength and low wettability by tuning the reaction parameters of soot‐templated surfaces.