Norbornene derivatives from a metal‐free, strain‐promoted cycloaddition reaction: New building blocks for ring‐opening metathesis polymerization reactions

The preparation of new ring opening metathesis polymerization (ROMP) monomers using a 1,3‐dipolar cycloaddition between aryl azides and norbornadiene is described. Various norbornenetriazolines, obtained through a solvent‐and catalyst‐free reaction, can subsequently be incorporated into polymer back...

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Published inJournal of polymer science. Part A, Polymer chemistry Vol. 53; no. 20; pp. 2357 - 2362
Main Authors Hobbs, Christopher E, Lin, Binhong, Malinski, Thomas
Format Journal Article
LanguageEnglish
Published Wiley 15.10.2015
Subjects
azides
polymerization
polymers
thermal degradation
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Summary:The preparation of new ring opening metathesis polymerization (ROMP) monomers using a 1,3‐dipolar cycloaddition between aryl azides and norbornadiene is described. Various norbornenetriazolines, obtained through a solvent‐and catalyst‐free reaction, can subsequently be incorporated into polymer backbones through ROMP reactions. Furthermore, thermal decomposition of the triazoline moiety can allow for further polymer functionalization. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2015, 53, 2357–2362
Bibliography:http://dx.doi.org/10.1002/pola.27691
ISSN:0887-624X
1099-0518
DOI:10.1002/pola.27691