Crystal structure and DFT study of bis-{( S )-2-[(2-hy-droxy-benzyl)-amino]-4-methyl-penta-noato-κ 2 N , O }(1,10-phenanthroline-κ 2 N , N ')nickel(II)

In the title compound, [Ni(C H NO ) (C H N )], the Ni cation shows a distorted octa-hedral coordination environment. It is formed by two N atoms from the phenanthroline ligand, as well as two N and two O atoms belonging to two 2-[(2-hy-droxy-benz-yl)amino]-4-methyl-penta-noate ligands. Complex mol-e...

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Published inActa crystallographica. Section E, Crystallographic communications Vol. 73; no. Pt 9; pp. 1393 - 1397
Main Authors Faizi, Md Serajul Haque, Dege, Necmi, Malinkin, Sergey
Format Journal Article
LanguageEnglish
Published England International Union of Crystallography 01.09.2017
Subjects
amine
crystal structure
C—H...π interactions
hydrogen bonding
leucine
nickel(II)
phenanthroline
Research Communications
salicylaldehyde
leucine
hydrogen bonding
phenanthroline
C—H⋯π inter­actions
nickel(II)
salicyl­aldehyde
crystal structure
amine
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Summary:In the title compound, [Ni(C H NO ) (C H N )], the Ni cation shows a distorted octa-hedral coordination environment. It is formed by two N atoms from the phenanthroline ligand, as well as two N and two O atoms belonging to two 2-[(2-hy-droxy-benz-yl)amino]-4-methyl-penta-noate ligands. Complex mol-ecules are connected into layers propagating along the plane hydrogen bonds formed by O atoms of carboxyl-ate and phenoxide groups, which are further connected into a three-dimensional motif.
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ISSN:2056-9890
2056-9890
DOI:10.1107/S2056989017012014