Identification of the sources of organic compounds that decalcify cement concrete and generate alcohols and ammonia gases

• Published in: Building and environment Vol. 44; no. 9; pp. 2000 - 2005
• Main Authors: Tomoto, Takashi, Moriyoshi, Akihiro, Sakai, Kiyoshi, Shibata, Eiji, Kamijima, Michihiro
• Format: Journal Article
• Language: English
• Published: Kidlington Elsevier Ltd 01.09.2009; Elsevier
• Subjects: Alcohol; Ammonia gas; Applied sciences; Black organic compounds; Buildings. Public works; Cement concrete; Concretes. Mortars. Grouts; Decalcification; Exact sciences and technology; General (composition, classification, performance, standards, patents, etc.); Materials; Black organic compounds; Cement concrete; Alcohol; Decalcification; Ammonia gas; Ammonia; Particle emission; Construction materials; Experimental study; Source; Organic compounds
• ISSN: 0360-1323; 1873-684X
• DOI: 10.1016/j.buildenv.2008.12.011

This study identifies the emission sources of various types of airborne organic compounds, which deteriorate cement concrete by penetrating into the concrete together with moisture. The study used high-performance liquid chromatography and gas chromatograph mass spectrometry. The results show that the types of organic compounds contained in decalcified cement concrete were very similar to those found in the total suspended compounds in the air, and that the source of the emissions was particles of exhaust from diesel vehicles and radial tires used in summer. Such organic compounds include substances suspected of having endocrine disrupting properties. Hydrolysis occurs when these substances penetrate into highly alkaline cement concrete, and leads to deterioration of the cement concrete and the release of alcohols and ammonia gases which pollute indoor air and may be a cause of the sick building syndrome.